ZnO基纳米多枝结构制备及物性研究-凝聚态物理专业论文.docxVIP

I I 摘 要 ZnO 作为第三代宽禁带半导体材料已经得到广泛研究。通过制备不同形貌 ZnO 纳米材料、ZnO 基复合材料可以充分利用纳米材料的优点，从而改善 ZnO 材料的性 能。本论文主要工作内容如下： （1）采用溶剂热法，通过调节水和乙醇混合液的比例制备了多种形貌的 ZnO 微 米结构。从我们的实验上可以得出结论：ZnO 的光学性质与其展现的形貌息息相关， 形貌差异能够引起 ZnO 局部的结晶质量不同，界面上的缺陷情况，材料表面的电荷 分布等差异，以上因素的协同作用最终影响了材料的光学性质。 （2）通过简单无催化的低温水浴方法合成多枝 ZnO 纳米/微米结构，这种由梭形 纳米/微米棒主干组成的纳米/微米结构周围围绕着六个径向导向的分支。本文分析了 其光学性质并详尽地探讨了可能的生长机理。 （3）利用操作简单的电化学沉积法制备海胆状 ZnO/In2O3 纳米复合结构。退火后 复合材料结晶性改善的同时，紫外发光增强，并在 443nm 观测到与 ZnO/In2O3 纳米复 合结构界面有关的发光峰。 （4）采取了三步的方法制备异质 Si/ZnO 纳米多枝结构。通过实验条件的改变选 择最优方案并研究了实验产物的光学性质。 关键词：ZnO 多枝 纳米复合结构 光学性质 II II ABSTRACT ZnO as the third generation of wide bandgap semiconductor materials have been widely studied.What can make full use of the advantages of nanomaterials is the preparation of different morphology ZnO nanomaterial, ZnO matrix composites, and the performance of the ZnO materials was improved. The main contents were as following: （1）ZnO microstructure was prepared by solvothermal method, and the morphology was altered only by adjusting the proportion of deionized water and ethanol in the solvent. It was found that the luminescence properties were related to the morphology of the ZnO materials, which was because that the morphology difference would lead to the differences on the crystal quality, interface defects, the charge distribution on the surface and the terminated lattice face of the crystal. The luminescence properties were finally determined by these factors together. （2）Without any catalysts-assisted，homobranched ZnOnano/microstructure had been synthesized via a simple low temperature water bath method. Such nano/microstructurewhich consists of shuttle-like nano/microrodbackbone was surrounded by six radial oriented branches. In addition, a detailed discussion regarding the probable growth mechanism is presented in this work. （ 3 ） Through an electrochemical deposition process, urchin-like ZnO/In2O3 nanocomposite structure was prepared. After annealing, the crystallinity of composite materials was improved