石英纤维有机硅树脂复合材料的制备及性能研究：材料学专业论文.docxVIP

哈尔滨工业大学工学硕士学位论文 哈尔滨工业大学工学硕士学位论文 II II Abstract Wave-transparent materials which have been extensive used in aerospace field requires excellent performance because of their special occasion. The use of traditional resins such as phenolic and epoxy as wave-transparent materials is limited, because their mechanical properties decreased severely as the temperature increased. However, organic silicone resin, whose heat resistance and dielectric properties are excellent have attracted much attention. In Russia, this resin has been used successfully in the tactical missile and space shuttles as the matrix of composites. It has been shown that, the Boron element added in silicone resin, forming Si-O-B bridge can improve its heat resistance further. The SiBOCH silicone resin can be prepared by the chemical reaction of B(OH)3 and poly-methyl ethoxy siloxane (PMES). The FT-IR analysis showed that the B element has been successfully connected to the silicon-oxygen alkane structure as Si-O-B bond. Meanwhile , its thermal properties has also been analyzed by TG. This paper is to seek an optimal preparation method of the composites with this prepared silicone resin as matrix and quartz fiber (cloth) who has good dielectric properties as reinforcement. The mechanical properties and microstructures were analyzed by three point method, SEM, FT-IR and TG-DTA. In the research of fiber cloth reinforce silicone resin composites, it shows that, the removal of the fiber sizing has a significant effect on the flexural strength of composites. Coupling agent used in the interface between fiber and matrix to form a chemical combination, can improve mechanical properties more effectively than method of heat treatment and acid etching, which are physical treatment. In addition, the coupling agent KH550 is more appropriate than KH560. With the increase of temperature, water and ethanol in the composites volatilize, the cleavage of Si-C bond can generate CO2 and H2O , Si-O bond break and small mol