煤基活性炭微波加热酸碱脱灰的研究-中国科技论文在线.PDFVIP

第3卷 第6期 中国科技论文在线 SCIENCEPAPER ONLINE 459 2008 年 6 月 煤基活性炭微波加热酸碱脱灰的研究 张 军，解 强，高小华，李兰廷，陈玉杰 （中国矿业大学化学与环境工程学院，北京 100083 ） 摘 要：本文选择典型的无烟煤基活性炭(TX-AC)和烟煤基活性炭(XP-AC)为研究对象，采用常规加热酸碱法 和微波加热酸碱法进行活性炭脱灰的研究。结果表明，微波加热较常规加热耗时少，处理后样品碘吸附值、亚 2 2 甲基蓝值高于常规法；TX-AC微波脱灰处理后的BET 比表面积由 621 m /g增大到 810.1 m /g ，平均孔径由 2.19 nm增大到 2.818 nm ，XP-AC微波处理后的平均孔径由 2.17 nm增大到 3.064 nm 。 关键词：无机化学工程；脱灰；微波加热；煤基活性炭；酸-碱洗 中图分类号：TM53 文献标识码：A 文章编号：1673－7180(2008)06 －0459 －6 Removal of inorganic matters from coal-based activated carbon by acid and alkali treatments under microwave heating ZHANG Jun ，XIE Qiang ，GAO Xiaohua ，LI Lanting ，CHEN Yujie (School of Chemical and Environmental Engineering, China University of Mining Technology, Beijing 100083) Abstract: Two typical commercial activated carbons TX-AC and XP-AC made from anthracite and bituminous coal, representatively, are treated by acid and alkali washing under conventional heating or microwave heating The results show that microwave heating is less time-consuming than conventional heating. The adsorption capacity of samples treated with microwave heating acid and alkali treatments for iodine and methylene blue is higher than that of samples treated with conventional heating; The BET specific area of TX-AC treated with microwave ash removing increase from 621 m2 2 /g to 810.1 m /g, the average pore size increase from 2.19 nm to 2.818 nm, meanwhile the average pore size of XP-AC treated with microwave increase from 2.17 nm to 3.064 nm. Key words: inorganic chemistry engineering ；removal of inorganic matters ；microwave heating ；coal-based activated carbon ；acid and