【毕业论文】多巴胺在聚溴甲酚绿修饰碳糊电极上的电化学行为的研究.doc

PAGE \* ROMAN \* MERGEFORMAT IV PAGE \* ROMAN \* MERGEFORMAT III 多巴胺在聚溴甲酚绿修饰碳糊电极上的电化学行为的研究 摘 要 运用循环扫描伏安法(Cyclic Voltammetry, CV)、线性扫描伏安法（Linear Sweep Voltammetry, LSV）研究了多巴胺（Dopamine, DA）在聚溴甲酚绿（Bromocresol green, BG）修饰碳糊电极（PBG/ CPE）上的电化学行为。结果表明，DA在裸碳糊电极(Carbon Paste Electrode, CPE)上的直接电化学氧化峰十分微弱，但在PBG/CPE上于0.21 V和0.31 V处分别出现一对可逆氧化还原峰，氧化峰电流大幅度增大，表明PBG/CPE对DA电化学氧化有显著的催化作用（本文主要研究0.31 V处的氧化峰），实验发现该催化氧化过程受吸附控制。用线性扫描伏安法测得DA催化氧化反应峰电流与其浓度在1.0×10-5～1.0×10-4mol·L-1 DA浓度范围内呈良好的线性关系。 关键词：多巴胺，聚溴甲酚绿，修饰碳糊电极，电催化氧化 Study Dopamine at Poly Bromocresol Green Modified Carbon Paste Electrode and its Electrochemical Behavior ABSTRACT Using circular voltammetry, Linear Sweep Voltammetry Study of dopamine at poly bromocresol green modified carbon paste electrode and its electrochemical behavior. Results show that the DA in the nude carbon paste electrode on the direct electrochemical oxidation peak is very weak, but PBG/CPE 0.21v and 0.31 v respectively, appear on a pair of reversible redox peaks, oxidation peak current is significantly increased, Indicates the PBG/CPE DA electrochemical oxidation catalysis of a significant(This paper mainly studies the oxide peaks 0.31 v), Experiments found that the catalytic oxidation process from adsorption control. By linear sweep voltammetry measurements Catalytic oxidation peak current and the concentration of DA in 1.0×10-5~1.0×10-4mol·L-1 DA range is a good linear relationship. KEYWORDS: dopamine, poly bromocresol green, modified carbon paste electrodes, Electrocatalytic oxidation 目 录 TOC \o 1-3 \h \z \u HYPERLINK \l _Toc358505588 摘 要 PAGEREF _Toc358505588 \h I HYPERLINK \l _Toc358505589 ABSTRACT PAGEREF _Toc358505589 \h II HYPERLINK \l _Toc358505590 1 综 述 PAGEREF _Toc358505590 \h 1 HYPERLINK \l _Toc358505591 1.1 课题研究的实验原理简介 PAGEREF _Toc358505591 \h 1 HYPERLINK \l _Toc358505592 1.1.1 循环扫描伏安法（Cyclic Voltammetry） PAGEREF _Toc358505592 \h 1 HYPERLINK \l _Toc358505593 1.1.2 线性扫描伏安法（Linear Sweep Voltammetry） PAGEREF _Toc358505593 \