壳聚糖三元接枝高分子絮凝剂对垃圾渗滤液生化处理出水....docVIP

PAGE 7 PAGE 6 壳聚糖三元接枝高分子絮凝剂对垃圾渗滤液生化处理出水的絮凝研究 李泗清第一作者： 第一作者：李泗清（1979－），男，广东梅州人，硕士生，研究水污染治理与控制 E-mail: HYPERLINK mailto:lisilsq@163.com lisilsq@163.com TEL：020邮政地址：广州华南理工大学环境科学与工程学院　邮编：510641 （华南理工大学环境科学与工程学院, 广东 广州510641） 摘要：采用壳聚糖三元接枝高分子絮凝剂（CAS）与聚合氯化铝（PAC）、磷酸镁铵沉淀法（MAP法）复配处理中山市老虎坑垃圾渗滤液生化处理出水。絮体粒径分布测试、絮体形态结构分析和zata电位测定结果表明CAS与PAC复配，可充分发挥CAS架桥和PAC电荷中和的协同作用，强化混凝过程，使细小的凝聚体形成体积庞大的絮状沉淀物，并在沉降过程中，网捕水体中的胶体颗粒，显著提高混凝效果。CAS和PAC的投加对NH4+-N的脱氮的贡献甚微。采用MAP法与CAS、PAC复配，当投加量分别为50mg/L CAS、500mg /LPAC、856mg /LMgCl2·6H2O、1509mg/L Na2HPO4·12H2O时，出水COD、色度分别小于300 mg/L、30倍，NH4+-N降至2 mg/L左右。 关键词：壳聚糖 PAC 垃圾渗滤液 氨氮 The Flocculation of Bio-treated Landfill Leachate by Chitosan Grafted Ternary Polymerization Flocculant LI Si-qing, HU Yong-you, CHENG Jian-hua (School of Environmental sciences and engineering, SCUT, Wushan Guangzhou 510641, China) Abstract: The effluent from Laohukeng (China) landfill leachate treatment plant was treated by modified chitosan (CAS), poly aluminum chloride (PAC), MgCl2·6H2O, and Na2HPO4·12H2O. It was found that combined use of CAS and PAC produced a synergistic effect. Viz., the flocculating and bridging of CAS and charge neutralization of PAC were co-functioned. The best dosage of CAS, PAC, MgCl2·6H2O, and Na2HPO4·12H2O was 50mg/L, 500 mg/L, 856 mg/L, and 1509 mg/L respectively. After being treated, the COD, NH4+-N and color value of the leachate was less than 300mg/L, 2mg/L, and 30 respectively with above-mentioned best dosage. NH4+-N in the leachate was removed in the form of MgNH4PO4 by MgCl2·6H2O and Na2HPO4·12H2O. The particle diameters measurement results indicated that using CAS and PAC together facilitated the formation of large flocs. Microscope photographs also showed that the flocs were more cross-grained and crassitude which meant more efficient treatment. Keywords:chitosan, PAC, landfill leachate，ammonia 对于垃圾渗滤液生化处理后出水，有研究者采用混凝法进行后续处理，主要为进一步除去渗滤液中难降解的有机污染物。例如，柴晓利等(2003)[参考文献 柴晓利，赵由才. 微生物絮凝剂用于垃圾填埋场渗滤后处理的研究. 黑龙江科技学院学报，2003，13(3): 6~9.]用50mg/L微