荔枝壳对Cr(VI)吸附性能研究.PDFVIP

第36 卷第3 期 Vol.36 No.3 冈山大学学报( 自然科学版) 2015 年5 月 May. 2015 Journal of Jinggangshan University (Natural Science) 49 冈山大学学报( 自然科学版) 49 章编号：1674-8085(20 15)03-0049-05 荔枝壳对Cr(VI) 的吸附性能研究 * 1,2 1,2 陈艺敏 ，陈建福 （1.漳州职业技术学院食品与生物工程系，福建，漳州 363000 ；2.农产品深加工及安全福建省高校应用技术工程中心，福建，漳州 363000 ） 摘 要：为考察荔枝壳对废水中 Cr(VI) 的吸附性能，用电镜对荔枝壳进行表征，并考察了 pH 、吸附剂用量、时 间和温度对吸附性能的影响。结果表明荔枝壳表面粗糙、凹凸不平，对Cr(VI)具有较强的吸附能力。在温度25 ℃ 下，震 吸附3 h ，荔枝壳对Cr(VI)去除率可达91.5% 。荔枝壳对Cr(VI)吸附的动力学和热力学研究结果表明，该 吸附过程符合准二级吸附动力学模型和Langmuir 等温方程。 关键词：荔枝壳；吸附；动力学；热力学 中图分类号：TQ153/X71/TS209 献标识码：A DOI:10.3969/j .issn.1674-8085.2015.03.011 ADSORPTION PROPERTIES OF LYCHEE EXOCARP ON CR(VI) * CHEN Yi-min1,2, CHEN Jian-fu1,2 (1. Department of Food and Biology Engineering, Zhangzhou Institute of Technology, Zhangzhou, Fuji an 363000, China; 2. The Applied Technical Engineering Center of Turther Processing and Safety of Agricultural Product s, Higher Education institutions in Fuji an Province, Zhangzhou, Fuji an 363000, China) Abstract: In order to investigate the adsorption properties of lychee exocarp on Cr(VI), the surface characteristics of lychee exocarp was revealed by SEM and the effects of pH, dosage, time and temperature on adsorption were investigated. The results indicated that the surface of lychee exocarp was rough and had strong adsorption ability to Cr(VI). At the temperature of 25 ℃, the removal efficiency of Cr(VI) reached 91.5% after 3 hours. According to the results of kinetic and thermodynamic studies, the adsorption process was consistent with pseudo-second-order adsorption model and Langmu