模拟酸雨对三明地区受重金属污染土壤的淋滤过程研究.PDFVIP

业环境科学学报 园园8熏 7穴1雪:0151-0155 允燥怎则灶葬造 燥枣 粤早则燥鄄耘灶增蚤则燥灶皂藻灶贼 杂糟蚤藻灶糟藻 模拟酸雨对三明地区受重金属污染土壤的 淋滤过程研究 1,2 1 3 1 1 丽华 袁朱志良 袁郑承松 袁 华 袁赵建夫 渊1. 同济大学污染控制与资源化研究国家重点实验室袁上海 200092曰 2. 三明学院化学与生物工程系袁福建 三明 365004; 3.三明市 环保局袁福建 三明 365004 冤 要院针对福建三明地区实际受重金属污染的土壤样品袁采用模拟酸雨淋溶土柱的试验方法袁研究了不同酸度模拟酸雨渊pH= 2.5尧3.6 和5.6冤对污染土壤中重金属元素的淋滤液性质的影响遥 结果表明袁随着模拟酸雨pH 值的降低袁淋滤液的电导呈递增变化袁 而淋滤液pH 值呈递减变化曰随着淋溶量的增加袁淋滤液电导逐渐下降袁而淋滤液pH 值呈现先迅速下降后逐渐升高的总趋势遥研究 发现袁模拟酸雨作用于该受重金属污染土壤时袁污染土壤中不同重金属呈现不同的溶出规 遥 淋滤液中锌尧镍尧铜尧铬和铅的含量均 随模拟酸雨pH 值的降低而增加袁但锌尧镍和铜的释放过程可分为快速释放和准稳定两个阶段袁铬和铅的释放过程则分为快速释放 和慢速释放两个阶段遥 相同pH 值模拟酸雨条件下袁该污染土壤中重金属累积释放量由大到小的顺序为Zn跃Cu跃Cr跃Ni跃Pb遥 pH越3.6 时袁每千克污染土壤中Zn尧Cu尧Cr尧Ni 和Pb 的最大累积释放量分别为750尧60尧0.9尧0.9 和0.48 mg遥 关键词：污染土壤；模拟酸雨；重金属；释放 中图分类号院载53 文献标识码院粤 文章编号院1672-2043(2008)01-0151-05 Leaching of Heavy Metals from Sanming Polluted Soil with Simulated Acid Rain 1,2 1 3 1 1 ZHANG Li-hua , ZHU Zhi-liang , ZHENG Cheng-song , ZHANG Hua , ZHAO Jian-fu (1.State Key Laboratory of Pollution Control and Resource Reuse, Tongj i University, Shanghai 200092, China; 2.Chemistry and Biology En原 gineering Department, Sanming College, Sanming 365004, China; 3.Sanming Environment Protection Bureau, Sanming 365004, China) Abstract: The soil column leaching model was used to study the leaching process of heavy metals with the simulated acid rain. The soil sam原 ples polluted by heavy metals were obtained from Sanming, Fuji an Province. The pH of the simulated acid rain was controlled in three levels of 2.5, 3.6 and 5.6. The tested metals included zinc, nickel, copper, lead and chromium. The investigation revealed that, with the pH decre原 ment of the acid rain, the conductivity of the