上海机动车尾气VOCs组成及其化学反应活性-上海交通大学大气.PDFVIP

DOI :0.5985/j .cnki.00 -3865.20 0.06.0 8 　　 VOCs 上海市机动车尾气VOCs 组成及其化学反应活性＊ 1,2 1 1 # 1 1 1 3 鲁　君 　王红丽 　陈长虹 　黄　成 　李　莉 　程　真 　刘　娟 (1., 200233;2., 200237; 3., 200030) 　　　-/, (VOCs) 。, (T VOC )(227.1 ±40.9)、(2 209.9 ± 3 1 228.0)μg/m ;T VOC 4.3 ～ 15.2 ;VOCs VOC s , VOCs 。 TVOC ·OH (17.21±4.49 )s-1, T VOC ·OH (300.37 ± 120.78)、(138.09±25.30 )s-1, T VOC ·OH , 70%。 C ～C , , 2 5 。 　　　　·OH 　 The composition and chemical reactivity of volatile organic compounds (VOCs)from vehicle exhaust in Shanghai, China 1,2 1 1 1 1 1 3 LUJ un , WAN G Hong li , CHE N Changhong , H UAN G Cheng ,LI Li , CHE N GZhen , LIUJ uan .(1.S hang- hai Academy of Environmental Sciences, Shanghai 200233;2.he School of Resources and Environmental Engineer- ing ,East China University of S cience and echnology , S hanghai 200237;3.Shanghai Environmental Monitoring Center, Shanghai 200030) Abstract:　The volatile organi ompounds (V OCs)pollution situation on the arterial roads and tunnels in Shanghai w as evaluated based on the anister sampling and GC/M S method.Results show ed that the mass on entra- tion of total volatile organi ompounds (TVOC)on arterial roads and tunnels were (227.1±40.9)and (2 209.9 ± 3 1 228.0)μg/m respe tively;The TV OC on entration in tunnels was 4.3-15.2 times of that on arterial roads.Con- ent rations of ethene, toluene, and ethane w ere higher than other ompounds both on the arterial roads and in tunnels. The ·OH-rea tivity of total volatile organi ompounds on the arterial roads, in the east Yan