固－液反应包膜尿素膜的微结构与红外光谱特征及-中国科技论文在线.PDFVIP

__________________________________________________________________________ 中国农业科学 2004,37（5）：704-710 Scientia Agricultura Sinica 固-液反应包膜尿素膜的微结构与红外光谱特征及 氮素释放特性研究 毛小云，冯 新，王德汉，孙克君，廖宗文 （华南农业大学资源环境学院，广州 510642） 摘要：应用扫描电镜和红外光谱仪对2种固－液反应型包膜尿素的膜结构及成膜机理进行分析，并结合水中 氮素溶出特性探讨了膜的结构特征与控释性能的关系。结果表明，固－液反应型包膜尿素膜由固体颗粒间的紧密排 列并通过液体胶联的多层叠加构成，叠加层间和单层固体颗粒间排列的紧密程度决定膜的孔隙度和孔径大小，且与 包膜材料特性有关。对膜谱学特征研究表明，固、液2种包膜材料在复合成膜过程中固体粉末表面的O-H与液体包 膜材料的双键位置有键合作用，这种键合作用是膜形成和保证膜强度的基础。2种包膜尿素氮素释放速度有较大差 别，且与膜结构密切相关，膜的孔隙度和孔径大小是决定氮素溶出速率的关键因素。 关键词：包膜尿素；膜；扫描电镜；红外光谱；氮素释放特性 Study on Membrane Microstructures and Characteristics of Infrared Spectra and Nitrogen Release of Solid-Liquid Reaction Coated Urea MAO Xiao-yun, FENG Xin, WANG De-han, SUN Ke-jun, LIAO Zong-wen (Colleg e of R esources and Env ironmental Scien ces, Sou th Chin a Agricu ltural University , Guang zhou 510 642) Abstract : The membrane micr ostructures and their form ing m echanism of two coated ureas formed through solid- liquid r eaction wer e observed by scanning electr on micr oscope and infrar ed sp ectra, the relat ion of the structural charact eri stics and the nitrogen r elease feature were al so di scu ssed combining with nitr ogen dissolution in water.The results showed that the membranes were made of solid particles, tightly connected each other and were piled up layer by layer through liquid glue . Porosity and aperture of membrane wer e determined by compactness of pilled layers and the particles in a single layer and also related to the characteristics of coating materials. Research of the infrared sp ectra of membrane, made of a solid powder and a liquid glue, has proved that O-H on the solid surface was bonded with the double bond of the liquid glue, thus forming membrane and keeping it stable. It is found that the two coated ureas show