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摘 要
磷是有害元素,对于高级别钢,除需要硫含量很低外,还需要磷含量控制在很低的水平。由于炼铁和炼钢脱氧过程为还原性气氛,脱磷条件较差,脱磷是纯净钢冶炼工艺的主要课题。本文从转炉脱磷的热力学分析入手,探讨了冶炼过程中温度、炉渣碱度、(FeO)对磷含量的影响,回磷的原因、影响因素及防止措施等,指出应控制炉渣碱度、终点温度、(FeO)在合理范围内,应重视钢水回磷问题。针对青钢目前转炉冶炼控制情况,并结合高碳钢中碳含量高的问题,提出了转炉双渣脱磷操作与冶炼终点低拉增碳相结合的脱磷冶炼控制工艺,以提高钢水的洁净度和产品质量。结果表明:通过良好的铁水条件;合理配料;严格控制前期枪位和倒渣时间;确保钢水终点碳含量在规定范围等技术措施,可有效降低钢中磷含量,为提高钢水洁净度和钢材质量创造有利条件。
关键词: 转炉冶炼;脱磷;双渣脱磷;热力学
Abstract
Phosphorus is harmful elements, in addition to very low sulfur content, but also need to control phosphorus content in a very low level for high-level steel. Dephosphorization clean steel smelting technology is the main topic, dephosphorization disadvantaged because of ironmaking and steelmaking process for deoxy reducing atmosphere. Dephosphorization converter from the thermodynamic analysis start of the smelting process of temperature, slag alkalinity, (FeO) on the content of phosphorus, phosphorus back to the reasons, factors and prevention measures that should be controlled slag alkalinity, temperature end , (FeO) within reasonable limits, should pay attention to steel phosphorus problem in this article. To improve the cleanliness of molten steel and the quality of products, made double-converter operation and smelting slag dephosphorization low end of Rafah by a combination of carbon Dephosphorization smelting process control, against the current converter Qinggang smelting and control of high-carbon steel in the carbon content High issue. The results showed that: favorable conditions to improve cleanliness of steel and steel quality can be created through technical measures, a good iron conditions, reasonable ingredients, strict gun-control early and inverted Jardine time to ensure that the end of molten steel in the provisions of the carbon content, can effectively reduce Steel phosphorus content.
Key words: converter smelting; dephosphorization; double slag dephosphorization;thermodynamics
目 录
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