水热法制备ZnO六棱柱及其结构、光学性质研究--毕业论文设计.doc

本科生毕业论文（设计） 中文题目 水热法制备ZnO六棱柱及其结构、光学性质研究 英文题目 The Preparation of ZnO ?Hexagonal Prisms with hydrothermal method and the Study of Its Structure and Optical Properties 学生姓名 班级 07级3班 学号 学 院 吉林大学物理学院 专 业 物理学 指导教师 职称 副教授 摘要 摘要 氧化锌（ZnO）是一种重要的 = 2 \* ROMAN II- = 6 \* ROMAN VI族半导体材料，ZnO的禁带宽度为3.37eV，激子束缚能为60meV。由于ZnO在光学、电学和磁学方面具有优良的性质， 它在光电子器件，光学催化剂，光电池等领域有着重要的应用。并且ZnO造价低廉，容易获得，纳米ZnO材料容易制备，因此纳米ZnO材料有着非常好的发展前景。 本文利用水热法制备了纯的纳米ZnO晶体，并通过SEM，XRD，PL对制备的样品进行了表征，分析了样品的形貌和光学特性。研究了不同温度对纳米ZnO晶体生长的影响。样品的SEM图表明样品中含有大量的六方纤锌矿结构的ZnO晶体，XRD谱线与标准ZnO的衍射谱线吻合的较好，PL图像表明ZnO晶体样品在紫外光区域具有较好的发光特性。 关键词 氧化锌；纳米材料；水热法；光致发光 Abstract Abstract ZnO is an important member of the compound semiconductors, with a band gap of 3.37eV and an excition binding energy of 60meV. Because ZnO possess unique optic, electronic and magnetic properties, It has been widely used in many different applications, such as optoelectronic devices, photo-degradation materials, as well as solar cells, etc. The price of ZnO is very cheap and ZnO nanostructures are easy to produce. So ZnO nanostructures have a good developing prospect. In this paper, pure ZnO nanostructures were prepared with hydrothermal method. The appearance and optic properties of the samples were characterized by SEM, XRD and PL methods. The influence of the temperature towards the growth of ZnO was studied in this paper. SEM pictures show that there are many wurtzite structure ZnO in the samples. XRD pictures are nearly the same as the standard ones. PL photos show that ZnO nanocrystals have superior illuminated properties in UV area. Key Words ZnO; nano material; hydrothermal method; photoluminescence 目录 目录 中文摘要 Abstract 目录 第一章 绪论．．．．．．．．．．．．．．．．．