水热合成Y2O3Eu3+纳米粒子及其发光性能研究--毕业论文设计.doc

PAGE II PAGE III 水热合成Y2O3:Eu3+纳米粒子及其发光性能研究 摘 要 本文采用以Y(NO3)3和Eu(NO3)3为原料，在不同反应温度， 不同矿化剂浓度的条件下，通过水热法及焙烧合成了Y2O3:Eu3+纳米粉体。对产物通过XRD、SEM等手段进行了表征，由XRD观测其结构成份，证明了生成的纳米粉体为Y(OH)3，再将其烧成Y2O3。实验进一步合成了不同浓度三价Eu离子掺杂的Y2O3:Eu3+纳米粒子，并且对Y2O3:Eu3+纳米粒子进行了荧光光谱分析。 关键词：水热合成，氧化钇，纳米粒子，发光 Hydrothermal synthesis and Photoluminescence Characterization of Y2O3:Eu3+ nanoparticles ABSTRACT A simple hydrothermal route has been used to prepare nanoparticles in different temperature and different pH by using Y(NO3) 3 and Eu(NO3) 3 as the source. The as-synthesized products were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscopy (SEM). From the structures of nanoparticles,the synthesized product is Y(OH)3,then thange it into Y2O3 through sintering. Y2O3:Eu3+ nanoparticles with different doping concentrations were Synthesized in further experiment,and Y2O3:Eu3+ nanoparticles was characterized by fluorescence spectrometry test. Key words:hydrothermal synthesis, yttria, nanoparticles, luminescence 目 录 TOC \o 1-3 \h \z \u HYPERLINK \l _Toc233195675 摘要 PAGEREF _Toc233195675 \h I HYPERLINK \l _Toc233195676 ABSTRACT PAGEREF _Toc233195676 \h II HYPERLINK \l _Toc233195677 目录 PAGEREF _Toc233195677 \h III HYPERLINK \l _Toc233195678 1 引言 PAGEREF _Toc233195678 \h 1 HYPERLINK \l _Toc233195679 1.1 纳米材料简介 PAGEREF _Toc233195679 \h 1 HYPERLINK \l _Toc233195680 1.1.1 纳米材料的概念 PAGEREF _Toc233195680 \h 1 HYPERLINK \l _Toc233195681 1.1.2 纳米材料的研究历史和发展趋势 PAGEREF _Toc233195681 \h 3 HYPERLINK \l _Toc233195682 1.2 稀土发光材料的研究历史和发展趋势及其发光机理 PAGEREF _Toc233195682 \h 4 HYPERLINK \l _Toc233195683 1.2.1 稀土纳米材料概述 PAGEREF _Toc233195683 \h 4 HYPERLINK \l _Toc233195684 1.2.2 稀土离子的特性 PAGEREF _Toc233195684 \h 5 HYPERLINK \l _Toc233195685 1.2.3 +3价态稀土离子的能级跃迁和光谱特性 PAGEREF _Toc233195685 \h 5 HYPERLINK \l _Toc233195686 1.2.4 稀土发光材料的优点 PAGEREF _Toc233195686 \h 6 HYPERLINK \l _Toc233195687 1.2.5 稀土发光材料的分类 PAGEREF _Toc233195687 \h 6 HYPERLINK \l _Toc233195688