聚苯乙烯固载聚乙二醇的合成及其对铬离子的吸附性能研究（毕业学术论文设计）.docVIP

本科毕业设计（论文） 聚苯乙烯固载聚乙二醇的合成及其 对铬离子的吸附性能研究 学 院 轻工化工学院 专 业 化学工程与工艺 年级班别 2003级化工（1）班 学 号 3103000007 学生姓名 指导教师 2007年6月8日摘 要 固载化聚乙二醇作为三相催化剂已有许多的学者在研究。在催化机理上的研究也已很深入，在有机合成方面的应用研究也很广范。关于固载化聚乙二醇合成条件方面的相关研究较少。将固载化聚乙二醇应用于对金属离子的吸附方面的研究也比较少。 聚苯乙烯接枝聚乙二醇树脂是在氢氧化钠溶液中将聚乙二醇接枝到氯甲基化的聚苯乙烯树脂上得到的。 本论文在前人的基础上讨论了合成聚苯乙烯固载聚乙二醇树脂的最佳条件，以及接枝产物对六价铬离子的吸附性能。我们以氢氧化钠为碱，甲苯为溶胀剂进行聚乙二醇固载化。得出反应最佳条件：反应时间9小时，碱浓度40％，用量100ml，甲苯用量20ml。聚苯乙烯接枝聚乙二醇树脂可以有效地吸附溶液中的六价铬离子，接枝产物的吸附能力与接枝的聚乙二醇量成正比，大孔型树脂接枝聚乙二醇－400的产物吸附效果最好。产物的红外光谱表明聚乙二醇接枝到了聚苯乙烯树脂上。热重分析图（DSC/TG）表明接枝产物具有很好的热稳定性。 关键词：聚苯乙烯树脂，固载，聚乙二醇，六价铬离子，吸附 Abstract The polystyrene supported polyethylene glycol (PEG) resin was investigated by many doctors as tri-phase phase transfer catalyst (TPPTC).The theory of it be used as catalyst were also being studied most ,it also being used in organic synthesis broad. But the investigation of the affected factors which synthesis the polystyrene supported polyethylene glycol resin were not more. And the studies of polystyrene supported polyethylene glycol resin that being used to adsorb the Cr6+ which in the solution was little. The polystyrene supported polyethylene glycol resin was prepared by grafting the polyethylene glycol onto the chloromethylated copolymer of styrene and divinylbenzene in the presence of concentrated sodium hydroxide solution. We investigated the factors which affect the synthesis of polystyrene supported polyethylene glycol resin and the products capability of adsorb the Cr6+.We use sodium hydroxide as alkali, toluene as solvent synthesis polystyrene supported polyethylene glycol resin. The optimal affected factors are: reaction times are 9 hours, the concentration of alkali is 40%, 100ml, polyethylene glycol is about 70mmol, and toluene is 20ml. the products can effectively adsorbed the Cr6+ in the solution. IR spectrum indicated that the polyethylene glycol (PEG) was grafting onto the polystyrene resin. DSC/TG plot indicated the prod