利用化学还原法快速合成近分散之Marcasite-中国鑛冶工程学会.PDF

利用化學還原法快速合成近分散之 Marcasite CuSe 與Berzelianite Cu Se 2 2 晶體及特性之研究 Ra p id Sy nt hes is of Ne a r ly Dis pe rs e d Ma rcas it e C uSe2 a nd Berzelianite Cu Se Crystallites Using Chemical Reduction Processes 2 1 2 3 4 C.T. Yang, H.I Hsiang, M.T. Sun, Y.C. Wu Nearly dispersed marcasite CuSe (m-CuSe ) 2 2 (triethylene glycol TEG) and berzelianite Cu Se (b -Cu Se ) cry stals were 2 2 (triethylenetetramine TETA) successfully prepared by thermal decomposition (polyvinylpyrrolidone PVP) of copper and selenium-triethylene glycol (TEG) m-CuSe b-Cu Se X solution u sing triethylen etetr amin e (TETA) as 2 2 (XRD) (SEM) th e r edu cin g agent an d p olyv iny lpyr r olidon e (TEM) X (PV P) a s th e capp in g ag ent . Th e cr y st allin e (XPS) - - structure, electronic, and copper selenide particle (UV-Vis-NIR) optical characterization were investigated u sing scanning electron microscopy (SEM), transmission TETA Cu electron microscopy (TEM), X-ray diffractometer Cu2+ Se Se22- (XRD), X-ray photoelectron spectroscopy (XPS) m-CuSe2 krutaite and UV-visible ab sorb ance sp ectra . The TETA CuSe2 TETA 0.147 M additive e