超临界流体的共溶剂效应和混合流体研究进展3.PDFVIP

第 18 卷 第 1 期 化　学　进　展 Vol. 18 No. 1 2006 年 1 月 PROGRESS IN CHEMISTRY 　Jan. , 2006 超临界流体的共溶剂效应和混合流体研究进展 牟天成1 　韩布兴2 ( 1 中国人民大学化学系 　北京 100872 ; 2. 中国科学院化学研究所分子科学中心 　北京 100080) 摘 　要 　共溶剂的出现极大地拓展了超临界流体的应用范围 ,推动了超临界流体科学与技术的发展。 本文从相行为和分子间相互作用热力学的角度 ,对相行为测定、量热技术、光谱技术和分子模拟等在超临界 流体中共溶剂效应的研究作了综述 ,主要介绍超临界流体中共溶剂的作用机理和混合流体在临界点附近热 力学性质研究 ,并对其未来发展方向进行了展望。 关键词 　超临界流体 　共溶剂 　分子间相互作用 　混合流体 ( ) 中图分类号: O6424 　文献标识码 : A 　文章编号 : 1005281X 2006 Progress in Cosolvent Effect of Supercritical Fluids and Mixed Fluids 1 2 Mu Tiancheng 　 Han Buxing ( 1. Department of Chemistry , Renmin University of China , Beijing 100872 , China ; 2. Center for Molecular Science , Institute of Chemistry , Chinese Academy of Sciences , Beijing 100080 , China) Abstract 　The use of cosolvents enlarges the application of supercritical fluids and speeds up the progress of the science and technology of supercritical fluids. The research of cosolvent effects in supercritical fluids using the technique of phase behavior , calorimetry , spectrum and molecular simulation are reviewed from the view of phase behavior and thermodynamics of the intermolecular interactions. The research on mechanism of cosolvent effects and the thermodynamic properties of mixed fluids near the critical point are introduced , the developiug trend of cosolvent effects and mixed fluid is prospected. Key words 　supercritical fluids ; cosolvents ; intermolecular interaction ; mixed fluids