（毕业论文毕业设计）-Cr2AlC陶瓷粉体的合成.docVIP

PAGE 摘 要 Cr2AlC陶瓷兼具了金属和陶瓷的综合性能，因此得到广泛关注。本次设计目的是利用Cr、Al、C摩尔比为 2:1.2:0.93三种原始粉末制备陶瓷。以NaCl作为熔剂，Cr2AlC与NaCl分别以1:1、1:2、2:1的质量比进行混合烧成，利用X射线衍射方法研究反应过程的物相演变过程。 将粉体在1250°C 、1350°C进行烧结，并利用X衍射仪进行粉体的物相分析。由1250°C时XRD图谱可知，当原料配比为Cr:Al:C＝2:1.2:0.93时，样品中形成Cr2AlC主相，同时也形成了大量的AlCr2相，而且还有残余的C。当Cr2AlC：NaCl=1:1时，形成Cr2AlC主相的同时，还形成了AlCr2相以及残余的C；当Cr2AlC：NaCl=1:2时，除了形成Cr2AlC主相还有残余的C；当Cr2AlC：NaCl=2:1时，形成的有Cr2AlC主相，还有大量的AlCr2相和少量的Cr7C3相。由1350°C时XRD图谱可知，当原料配比为Cr:Al:C＝2:1.2:0.93时，样品中形成Cr2AlC主相，同时也形成了大量的AlCr2和Cr7C3相。 关键词： Cr2AlC陶瓷 NaCl含量 X－射线衍射分析 Title Effect of NaCl on the Cr2AlC ceramic powder composites Abstract: Cr2AlC ceramic has the compressive properties of metal and ceramics, so that it can earn wide public concern. The purpose of this design is to fabricate single phase Cr2AlC ceramic, using Cr，Al and C which the atomic ratio is 2:1.2:0.93 as starting materials. NaCl as flux, Cr2AlC with NaCl were 1:1,1:2,2:1 quality than mixed firing , using X-ray diffraction method, the reaction process , phase evolution. Sintering the powder at 1250 ° C , 1350 ° C , and powders using X-ray diffraction phase analysis . 1250 ° C XRD patterns shows that when the ratio of raw materials for the Cr:Al:C=2:1.2:0.93 of the sample Cr2AlC the main phase , but also the formation of a large number of AlCr2 phase , but also the residual C When Cr2AlC:NaCl=1:1 when the formation Cr2AlC main phase AlCr2 phase and the residual C ; when Cr2AlC: NaCl = 1:2 , in addition to the formation of the Cr2AlC main phase of residual C ; Cr2AlC : NaCl = 2:1 , the formation of have Cr2AlC main phase , there are a lot of AlCr2 phase and a small amount of Cr7C3 phase . 1350°C.XRD patterns shows that when the ratio of raw materials for the Cr:Al:C=2:1.2:0.93 of the samples formed Cr2AlC main phase , but also the formation of a large number of AlCr2 and Cr7C3. Keywords ：Cr2AlC ceramic NaCl content X-Ray diffraction 目 次 TOC \o 1-3 \h \z \u HYPERLINK \l _Toc325297575 1 引言 PAGEREF _Toc325297575 \h 1 HYPER