微波条件下塑料包装中内分泌干扰物的迁移-包装工程.PDF

包装工程 第36卷 第11期 10 PACKAGINGENGINEERING 2015年6月 微波条件下塑料包装中内分泌干扰物的迁移 李翠翠，林雯，黄崇杏，闫蒙蒙，赵媛，陈宜昭 （广西大学，南宁 530004） 摘要：目的目的 研究微波加热条件下塑料食品包装中9种内分泌干扰物的迁移规律及影响迁移的因 素。方法方法 利用气相色谱-质谱联用分析经微波处理和超声萃取后的塑料样品。结果结果 DEA和BHA 在塑料样品中的初始浓度很低，其余7种内分泌干扰物均发生迁移。对比迁移前后的扫描电镜图片 发现迁移后的塑料表面会溶胀发白。迁移单元在降温过程中，初期迁移率快速增大，随着时间的延 长，迁移率的增幅减小，最后达到迁移平衡。结论结论 内分泌干扰物的迁移率随着微波功率和微波时 间的增大而增加，加热初期迁移率增加比较慢，后期迁移率增速比较大。 关键词：内分泌干扰物；微波加热；迁移；气相色谱-质谱联用 中图分类号：TS207 文献标识码：A 文章编号：1001-3563（2015）11-0010-06 Migration of EDCs in Plastic Packaging under Microwave Heating LICui-cui，LINWen，HUANGChong-xing，YANMeng-meng，ZHAOYuan，CHENYi-zhao （Guangxi University ，Nanning 530004 ，China） ABSTRACT ：This paper analyzed the migration regularity and influencing factors of nine kinds of endocrine disrupting chemicals (EDCs) under microwave heating. The plastic samples, treated by microwave and ultrasonic extraction, were analyzed by GC-MS . The initial concentrations of DEA and BHA in plastic samples were low and the other 7 kinds of endocrine disrupting chemicals all migrated. Comparison of SEM photographs before and after migration showed that the surface of migrated plastics became swelling and whity. In the process of cooling, the migration rate increased rapidly at the beginning, but then the amplification of migration rate decreased over time. In the end, the migration reached equilibrium. The migration rates of endocrine disrupting chemicals were increased with the increase of microwave power and action time. The migration rates increased slowly at first ，then rapidly in later period. KEY WORDS ：endocrine disrupting chemicals ；microwave heating ；migrati