（毕业学术论文设计）-无导向剂水热合成NaY型分子筛及其催化性能研究论文.docVIP

PAGE \* MERGEFORMATII PAGE \* MERGEFORMATI 无导向剂水热合成NaY型分子筛及其催化性能研究 摘 要 以硅酸钠和铝酸钠为主要原料，在无导向剂条件下，采用直接晶化法制备了NaY型分子筛。考察了陈化时间、晶化时间、晶化温度、体系的水含量和n(Na2O)/n(SiO2)等因素对分子筛结构和形貌的影响。采用X射线衍射(XRD)对样品进行了表征。结果表明：n(Na2O)/n(SiO2)和n(H2O)/n(Al2O3)影响产物结晶度,当n(Na2O)/n(SiO2)=1.0、n(H2O)/n(Al2O3)=160时产物结晶度较好。用最佳水热条件下合成的NaY型分子筛负载Pd2+，得到Pd/NaY催化剂，研究Pd/NaY催化剂对苯甲醇氧化为苯甲醛的催化性能。 关键词： Pd NaY 无导向剂 苯甲醇 氧化反应 Study of NaY synthesis by hydrothermol method without seed and its catalytic performance ABSTRACT Using sodium silicate and sodium aluminate as raw materials, NaY zeolites were synthesized by direct crystallization without seed gel. The hydrothermal synthesis conditions including aging time, crystallization temperature and time, water content andn(Na2O)/n(SiO2) in the system were investigated. The synthesized NaY were characterized by X-ray diffraction (XRD). The results indicate that increasing aging time favors the formation of more nuclears, but too long aging time leads to increase particle size of zeolite. High crystallinity NaY are synthesized when n(Na2O)/n(SiO2) and n(H2O)/n(Al2O3) are 1.0 and 160, respectively. The Pd/NaY were synthezied by impregnation of Pd2+ onto NaY. The catalytic performance of Pd/NaY was studied for the oxidation of benzyl alcohol to benzaldehyde. Keywords：Pd NaY non-seed benzyl alcohol oxidation 目 录 TOC \o 1-3 \h \z \u HYPERLINK \l _Toc295485778 摘 要 PAGEREF _Toc295485778 \h I HYPERLINK \l _Toc295485779 ABSTRACT PAGEREF _Toc295485779 \h II HYPERLINK \l _Toc295485780 第一章 文献综述 PAGEREF _Toc295485780 \h 1 HYPERLINK \l _Toc295485781 1.1 NaY分子筛的研究成果及发展前景 PAGEREF _Toc295485781 \h 1 HYPERLINK \l _Toc295485782 1.2 NaY分子筛的合成方法 PAGEREF _Toc295485782 \h 2 HYPERLINK \l _Toc295485783 1.2.1 酸浸偏高岭土-碱水热反应体系NaY分子筛的合成 PAGEREF _Toc295485783 \h 2 HYPERLINK \l _Toc295485784 1.2.2 导向剂法 PAGEREF _Toc295485784 \h 2 HYPERLINK \l _Toc295485785 1.2.3 NaY 分子筛的微波合成[8] PAGEREF _Toc295485785 \h 2 HYPERLINK \l _Toc295485786 1.2.4无导向剂，以硅酸钠和铝酸钠水热直接合成NaY PAGEREF _To