氨水—硫酸铵体系中Mextral54-100萃取铜研究.docVIP

doi：10.3969/j.issn.1007-7545.2018.11 doi：10.3969/j.issn.1007-7545.2018.11.003 曾磊1，王成彦1,2，马保中1,2，陈永强1,2，邢鹏1 （1.北京科技大学 冶金与生态工程学院，北京 100083； 2.稀贵金属绿色回收与提取北京市重点实验室，北京 100083） 摘要：以Mextral 54-100为萃取剂，对某铜铝废料经氨性体系浸出后所得料液进行溶剂萃取，回收金属铜。分别考察了萃取剂浓度、相比、时间、水相初始pH对铜萃取的影响。溶剂萃取最优工艺条件：萃取剂体积浓度40%、相比O/A=1/1、混合时间4 min。此条件下单级萃铜能力达29.66 g/L。经过萃取、洗涤后，采用170 g/L硫酸进行反萃，铜反萃率达92.59%。通过McCabe-Thiele图解法确定了萃取段的理论级数，并进行了二级模拟逆流试验验证，最终萃余液含铜约0.06 g/L。 关键词：Mextral 54-100；β-二酮；溶剂萃取；铜 中图分类号：TF811 文献标志码：A 文章编号：1007-7545（2018）11-0000-00 Solvent Extraction of Copper from Ammoniacal/Ammonium Sulfate Medium with Mextral 54-100 ZENG Lei1, WANG Cheng-yan1,2, MA Bao-zhong1,2, CHEN Yong-qiang1,2, XING Peng1 (1. School of Metallurgical and Ecological Engineering, University of Science and Technology Beijing, Bejing 100083, China; 2. Beijing Key Laboratory of Green Recycling and Extracting Rare and Precious Metals, Beijing 100083, China) Abstract：Solvent extraction of copper from ammoniacal/ammonium sulfate medium using Mextral 54-100 was investigsted. Effects of extractant concentration, phase ratio, extraction time and pH value of initial leach solution on copper extraction were examined. The results show that capacity of one-stage copper extraction is 29.66 g/L under the optimum conditions including 40% volume concentration of extractant, phase ratio of O/A=1/1, and extraction time of 4 min. Copper stripping rate with 170 g/L H2SO4 is 92.59% from loaded organic phase. Theoretical stage of extraction is determined by of McCabe-Thiele Isothermy Graphic Method. After two-stage countercurrent extraction, the simulation results correspond with the data, and copper concentration in raffinate is about 0.06 g/L. Key words：Mextral 54-100; β-diketone; solvent extraction; copper 废杂铜的处理方法主要有火法[1]、湿法[2-3]以及直接电解[4]。其中湿法工艺主要是通过浸出-萃取-电积流程实现金属的回收。在湿法工艺中，氨性体系浸出常用于氧化铜精矿[5-6]和电子印刷线路板[7]以及电子废弃物[8]的处理，所得浸出液经溶剂萃取后用于电积。Mextral 54-100是一种螯合型萃取剂，普遍用于印制电路板的氨浸出液、废铜、铜合金类、铜/铅渣滓和和某些硫化铜精矿中萃取铜[9]。Lix54和Mextral 54-100同属于β-二酮类萃取剂，但前者在氨性体系下萃取金属已经得