丁胺黑药测定几种方法.docVIP

几种测定选矿废水中丁铵黑药含量的方法研究 郭超1，柏韬2,3，徐风4 （1.云南省冶金研究设计院，云南·昆明 650031 2.东北大学材料与冶金学院，辽宁·沈阳 110819 3.中南大学冶金科学与工程学院，湖南·长沙 410083 4.烟台鹏晖铜业有限公司，山东·烟台 264002） 摘要：本文通过分析对比紫外分光光度法、亚铁灵显色-可见光分光光度法、铜试剂显色-可见光分光光度法三种对丁铵黑药的测定方法，发现紫外分光光度法极易受到共存杂质离子的干扰，严重影响测定结果；而亚铁灵显色-可见光分光光度法虽能测定出丁铵黑药的浓度，但在锌离子共存的条件下，干扰很大，无法进行正常测定，并且亚铁灵试剂（邻菲咯啉）见光不稳定，易分解。通过实验结果发现采用铜试剂显色-可见光分光光度法对丁铵黑药浓度进行测定，杂质离子对其测定的影响不大，加标回收率在在95.0%-109.8%之间，精密度考察的变异系数为3.46%。 关键词：丁铵黑药，分光光度法，选矿药剂 Several Researches on Determining The Concentration of Ammonium Dibutyl Dithiophosphate in The Beneficiation Wastewater Guo Chao，Bai Tao，Xu Feng (1.Yunnan Metallurgical Research and Designing Institute, Kunming, Yunnan650019, China; 2. School of Materials and Metallurgy Northeastern University, Shenyang, Liaoning100819, China; 3. School of Metallurgical Science and Engineering, Central South University, Changsha 410083, China; 4. Yantai Penghui Copper Industry Co., Ltd, Yantai, Shandong264200, China) ABSTRACT：Through the comparative analysis of ultraviolet spectrophotometry and ferroin colorimetric spectrophotometry, copper reagent colorimetric spectrophotometry, three measurement methods of ADDP, we found that ultraviolet spectrophotometry vulnerable to coexist impurity ions interference, seriously effected on the determination results; Ferroin colorimetric spectrophotometry is able to determine the pure butyl ammonium the concentration of the black medicine, but in zinc ion coexistence, interference is very serious under this condition and cant normally determine, and also ferrous and ferroin (5-amino-1,10-phenanthroline) is not stable in the light and easy to resolve. Finally we found that copper reagent colorimetric spectrophotometry determination of concentration of ADDP was not influenced by the coexist impurity ions, the recovery rate by standard addition method is between 95.0% and 109.8%, and the variation coefficient by the accuracy test is 3.46%. Key words: ammonium dibutyl dithiophosphate(ADDP), spectrophotometry, mineral processing rea