中和胺性能测定.docVIP

PAGE 22 中和胺的性能测定 摘要 中和胺作为调节蒸汽回流冷凝水的pH物质。无论有机胺的调节能力怎么好，但它总存在部分缺陷，在冷凝水系统中，胺在气相和液相中的分配比与碱性或中和容量一样重要。中和胺的选择必须根据它们“捕捉”酸性污染物的分配特征来决定，这种选择必须适合冷凝水系统和工艺介质污染物。在120℃左右的回流冷凝水中，吗啉是一种主要分散在液相中的胺，而环己胺则大部分仍然留在蒸汽中，故将将两种胺以某种比例混合才能将120℃左右的回流冷凝水的pH调控好；然而，仅有两种原料胺的中和胺总也不能摆脱调节范围较窄的瓶颈，这就需要另一种胺的加入来解决问题，也就是调节范围较宽的N-甲基二乙醇胺。将这三种胺以89:7:4的比例混合起来，混合胺相互协调所表现出来的调节能力与实际需要即相差无几了。 关键词：环己胺，吗啉，N-甲基二乙醇胺，吡咯烷，中和胺 THE PERFORMANCE MEASUREMANT OF NEUTRAILIZING AMINE ABSTRACT Uses for to adjust the steam backflow condensed water the neutral amine not to be exceptional. Regardless of one kind of amine’s adjustment ability is how good, but it always has the partial flaws, in the condensation aqueous system, the amine is equally more important than in the vapor phase and the liquid phase assignment and the alkalinity or the neutral capacity. The neutral amine’s choice must according to them “the capture” the acidic pollutant assignment characteristic to decide that this kind of choice must suit the condensation aqueous system and the craft medium pollutant. In 120℃ about backflow condensed water, the morpholine is one kind mainly disperses in the liquid phase the amine, but the cyclohexylamine majority of still kept in the steam, therefore just two kind of amines can regulate by some kind of proportion mix 120℃ about backflow condensed water pH; However, looks like two people to be the same, will have the friction unavoidably steadily together in the time, two raw material amine’s neutral amine always could not only get rid of the regulation band narrow bottleneck, this needed another kind of amine to join solves the problem, was also the regulation band wide N-methlyldiethanolamine. Mixes these three kind of amines by some kind of proportion, the mixed amines proportion by 89:7:4, the mixed amine intercoordination displays adjustment ability and the actual need have been almost the same. KEYWORDS：cyclohexylamine, morpholine, N-mathyldiethanolamine, tetrahydropyrrole, neutral amine 目录 TOC \o 1-3 \h \z \u