层状钙钛矿型La2Ti2O7陶瓷的制备及其多铁性研究-材料物理与化学专业论文.docx

华中科技大学硕士学位论文 华 中 科 技 大 学 硕 士 学 位 论 文 II万方数据 II 万方数据 0.0018 emu/g 和 0.38μC/cm2。 接着，在 B 位引入 Fe 离子，探索 Fe 离子的引入对 La2Ti2O7 样品的 XRD、P-E 和 M-H 曲线等影响。研究结果表明低掺杂量为单相，掺杂量大于 0.04 就有 La2/3TiO3 杂相出现；同纯相的 La2Ti2O7 相比，引入 Fe 离子的样品的铁电性减弱，但当 Fe 离 子浓度上升时，样品的铁电性逐渐增强，这是因为高掺杂量样品中出现 La2/3TiO3 的 缘故；通过比较不同 Fe 离子浓度的样品的 M-H 曲线，发现当 Fe 离子浓度上升时， La2Ti2O7 样品的铁磁性逐渐增强。 （3）在 La2Ti2O7 样品的 A 位掺杂 Nd 离子，同时在 B 位掺杂 8%的 Mn 离子， 研 究 掺 杂 样 品 的 物 相 、 磁 性 和 铁 电 性 。 采 用 固 相 法 合 成 了 一 系 列 的 La2-xNdxTi1.92Mn0.08O7(0≤x≤0.4)陶瓷样品，X 射线衍射结果表明，所有样品均为单相， 表明 Nd 和 Mn 能够同时完全进入到 La2Ti2O7 晶格中去；与 La2Ti1.92Mn0.08O7 陶瓷样 品相比，Nd 掺杂能够起到改善样品铁电性的作用；室温磁滞回线的结果表明，Nd 的引入使得 La2Ti1.92Mn0.08O7 陶瓷逐渐由铁磁性变为顺磁性。 关键词：多铁性材料，La2Ti2O7，铁电性，铁磁性 PAGE IV万方数据 PAGE IV 万方数据 Abstract Multiferroics refer those materials which process two or more primary ferroics in the same phase. The so-called primary ferroics refer ferroelectricity, ferromagnetism and ferroelasticity, which have been widely studied. What’s more, ferromagnetic and ferroelectric ordering exist coupling, which means that magnetic field can control polarization and electric field can control magnetization. The features described above make it possible to be applied in the new multi-functional devices. In recent years, multiferroics have been of particular interest in the field of condensed matter physics and materials science. Rare earth titanate R2Ti2O7 (R=rare earth) has many physical properties and broad application prospects. If R is La or Nd, it has a perovskite layered structure. While R is Sm~Lu or Y, it has a pyrochlore-type structure. For La2Ti2O7 with monocline, people have more focused on its photocatalytic properties and photoluminescent properties. But its multiferroic properties are less studied. This article has studied the effect of sintering condition on ferroelectric properties of La2Ti2O7 ceramic. On above base, we prepare doped La2Ti2O7 to make it have outstanding multiferroic properties at room temperature. The main contents are as follows: A series of La2Ti2O7