多孔锡电极的制备及其用于CO2电化学还原性能的研究-化学工艺专业论文.docxVIP

万方数据 万方数据 both the porous Sn electrode and the Sn plate electrode, which revealed that the rate-determining step was same on both electrodes, which was one initial electron transfer to CO2 to form a surface adsorbed ·CO2ads-. The results of electrochemical impedance spectra from CO2 electroreduction on the porous Sn electrode indicated that electrchemical impedance spectra included three parts: high frequency Warburg controlled area, middle frequency capacitive loop of faraday resistance and low frequency capacitive loop of diffusion of adsorbed speciese. Finally, investigationg of reusability resulted that the eletrocatalytic performance of the porous Sn electrode decreased, and it maybe caused by deposits loss. Keywords: Carbon dioxide, Electroreduction, Porous Sn electrode, Formic acid 目录 HYPERLINK \l _bookmark0 第一章 文献综述..........................................................................................................1 HYPERLINK \l _bookmark1 1.1 温室气体 CO2 1 HYPERLINK \l _bookmark2 1.2 CO2 的基本性质 1 HYPERLINK \l _bookmark3 1.2.1 物理化学性质..............................................................................................1 HYPERLINK \l _bookmark4 1.2.2 CO2 在水溶液中的溶解度和种类 2 HYPERLINK \l _bookmark5 1.2.2.1 化学反应和平衡常数............................................................................3 HYPERLINK \l _bookmark6 2-  HYPERLINK \l _bookmark6 溶液中 CO2 的溶解度 4 HYPERLINK \l _bookmark7 1.2.3 电极界面 pH 值的变化 5 HYPERLINK \l _bookmark8 1.2.4 在 CO2/HCO3-/CO32-系统中电势与 pH 的关系图 5 HYPERLINK \l _bookmark9 1.3 CO2 的利用现状 6 HYPERLINK \l _bookmark10 1.3.1 CO2 的化学转化 6 HYPERLINK \l _bookmark11 1.3.2 新型 CO2 还原方法 7 HYPERLINK \l _bookmark12 1.4 CO2 的电化学还原 8 HYPERLINK \l _bookmark13 1.4.1 CO2 电还原的理念 8 HYPERLINK \l _bookmark14 1.4.2 CO2 电还原的原理和动力学 9 HYPERLINK \l _bookmark15 1.4.2.1 CO2 电还原反应的原理 9 HYPERLINK \l _bookmark16 1.4.2.2 CO2 电还原反应的动力学 11 HYPERLINK \l _bookmark17 1.4.3 CO2 电还原反应的进展 12 HYPERLINK \l _bookmark18 1.4.3.1 不同电极上 CO2 还原的产物 12