新型抗烧蚀酚醛树脂的研究.PDF

31 - Study on a New type Ablative Phenolic Resin , , (, 250061) - , - , - EI Hua zhen ANG Cheng guo ANG Hai qing (School of Material Science and Engineering Shandong University Jinan, , 250061, China) : (F) / (P) (o/p) , , , , , F/P 1. 61. 8, /, , : ; ; ; : TQ433.4: A: 1001-4381 (2003) 03-0031-04 Abstract : Phenolic resins which had various orth/para hydroxy methyl ratios were synthesized by use of complex alkali catalysts and under various ratios of formaldehyde/phenol.The fused-ring transition mechanism of carbonization of phenolicresin couldbe optimized by altering the orth/para crosslink degree, the course of carbonization could go slowly and steadily, and the char yielded show a high tendency towards graphitization under high temperature and so ablative ability could, . / 1.61.8, be improved hen theformaldehyde phenol ratios were in the phenolic resins ablation morphological appearanceswere ameliorate andtheir char yieldsand ablation ratesof thecomposite, were relatively ideal. Key words: heat protection material phenolic resin ablate composite; ; ; / 1. 1 , (P): , ; , (F) : , ; , , : ; : AR, 1. 2 /, , , , , [1] , 20min, 8090 , , [2] , , -1 , P -1 , P , 1624 ,