多元结构超疏水表面的制备及其在冷凝条件下的润湿性研究-材料学专业论文.docxVIP

并采用高压喷射的方法将 PDMS/纳米 CaCO3 涂料喷至塑料片材表面， 在涂料完全干后，即可获得超疏水 PDMS/纳米 CaCO3 涂层。观察了 冷凝条件下 PDMS/纳米 CaCO3 涂层的润湿性变化，结果表明，使用 高压喷射的方法获得的 PDMS/纳米 CaCO3 涂层在冷凝条件下的润湿 性变化较大，由超疏水表面变成了亲水表面，并对其润湿性下降原因 进行了分析。 (5) 将模板法与腐蚀法相结合，提出一种新颖的方法在铁表面获 得类竹叶表面的微纳多元结构，将获得的类竹叶微纳多元结构的铁片 表面用硬脂酸修饰后，其表面的微纳多元结构变得与竹叶表面的微纳 多元结构更加相似，接触角和滚动角测试表明，经硬脂酸修饰后的铁 片表面具有很好的超疏水性能。 关键词：超疏水，多元结构，冷凝，润湿性 II ABSTRACT Superhydrophobic surfaces have drawn attention of scientists from various fields due to their excellent properties, such as self-cleaning, anti-corrosion, drag-reduction, and so on. Many effects have been devoted to the study of fabrication and properties of superhydrophobic surfaces. However, only a few studies reported whether superhydrophobic surface can retain superhydrophobicity under any condition. Lately, some scientists found that superhydrophobic surfaces may lose superhydrophobicity under condensation. The lost of superhydrophobicity means other fine properties of superhydrophobic surface will lose as well. Thus, we explored the relationship between the multi-scale structure and the wettability of superhydrophobic surfaces under condensation, and try to discover the rule. The main contents are as follows: Two type of LDPE coatings were obtained by a simple and novel approach, the surface structure of which were different. One of them is superhydrophobic LDPE coating with high sliding angle and the other is superhydrophobic LDPE coating with low sliding angle. Then the wettability test of these two type superhydrophobic LDPE coating and smooth LDPE coating were performed under condensation. The results show that the water repellency of the superhydrophobic LDPE coating with low sliding angle is much better than the superhydrophobic LDPE coating with high sliding angle, while the water repellency of the superhydrophobic LDPE coating with high sliding angle is only a little better than the smooth LDPE coating. The result also indicates that the change of hierarchical structure on superhydrophobic surface wi