石家庄污灌区水土的环境中有机污染物分析.docVIP

石家庄污灌区水土的环境中有机污染物分析 　　摘要：为了查明污灌区水土环境中的有机污染物的自然衰减作用，采集了1组污灌渠水样，9组地下水样；1组污灌渠底泥样，8组土壤样。本次检测挥发性有机污染物26项，有机氯农药9项，多环芳烃1项。检测结果表明，污灌区水土环境中有机污染物均具有较强的自然衰减作用，其中浅层地下水中氯仿的衰减率达73??3%，而六六六的衰减率达100%；土壤在取样范围内（50 m）检出的有机污染物主要有氯仿、苯、甲苯、乙苯及二甲苯、六六六、六氯苯、DDT及多环芳烃-苯并［α］芘，随着深度的增加其含量也随之减小，甲苯的衰减率和二甲苯的衰减率较弱分别为62??5%和87??5%，其余各项均为100%。 　　关键词：污灌；有机污染物；自然衰减作用 　　中图分类号：X132 文献标识码：A 文章编号： 　　1672-1683（2010）06-0053-03 　　Analysis of Organic Pollutants in Soil and Water Environment in Sewage Irrigation Areas of Shijiazhuang 　　YIN Mi-ying,ZHANG Sheng,LI Zheng-hong,MA Lin-na,HE ze,NING Zhuo,ZHANG Cui-yun 　　(The Institute of Hydrogeology and Environmental Geology,Chinese Academy of Geological Sciences,Shijiazhuang 050061,China) 　　Abstract:To find out the natural attenuation in soil and water environment in sewage irrigation areas, one group of water samples and sediment samples in wastewater irrigation channel,nine groups of groundwater samples and eight sets of soil samples were collected. 26 kinds of volatile organic compounds,nine kind organochlorine pesticides,and one kind polycyclic aromatic hydrocarbon were analyzed during this time.The result showed that,there was strong natural attenuation in the soil and water environment in the sewage irrigation.The ratio in attenuation of chloroform and benzene hexachloride was 73??3%and 100% in the shallow groundwater;while the soil in the sampling depth range(5??0 m) was mainly chloroform benzene,toluene,p-xylene/m-xylene,benzene hexachloride hexachlorobenzene,DDT and polycyclic aromatic hydrocarbons-benzo ［α］ pyrene，the concentration decrease with the depth in the soil, The ratio in attenuation of toluene and xylene was 62??5% and 87??5%,the rest were all 100%. 　　Key words: sewage irrigation;organic compounds;natural attenuation 　　 随着工农业的迅速发展，大量的有机污染物进入环境介质（大气、水、土壤等），有些污染物质能够在环境中长期存在，进而对人类健康和环境造成严重危害。一方面是环境中的有毒有机污染物对人类产生直接危害，对人类的生存繁衍和可持续发展构成十分严重的威胁；另一方面是对环境造成难以修复的破坏，间接影响到人类的生存发展。 　　1999年-2002年，中国地质调查局在华北平原某城市近郊开展的地下水有机污染调查，在地下水中检出有机物36项，其中单环芳烃12项、