《负载TiO2的介孔吸附剂降解工业染料废水》-毕业学术论文设计.docVIP

武汉工程大学本科毕业论文 Ⅰ 摘 要 工业染料废水，成分复杂，色度高，难降解的物质多，给环境和人类的健康带来了严重的威胁。但现阶段吸附材料仍旧存在再生困难、二次污染等缺点。介孔材料以其具有大量的孔道和空穴，比表面积大等特点被广泛的应用于工业染料废水的净化。TiO2具有很强的光催化性能，对有机物的降解选择性低且能使之彻底矿化、无二次污染。通过水热法一步合成了负载TiO2的介孔吸附剂, 并通过FTIR, XRD确证了材料的成分, TEM以及氮吸附测试结果表明, 材料的孔径可达5.23nm, 比表面积798.97m2/g。将所制备的介孔吸附剂应用于光催化染料废水中的罗丹明B和亚甲基蓝, 结果表明, 仅10min样品对罗丹明的最大吸附量可达20.54mg/g, 对亚甲基蓝的最大吸附量可达23.79mg/g。对罗丹明需50分钟催化作用, 降解率达99%以上, 对亚甲基蓝只需25分钟催化作用, 降解率达99%以上。 关键词：染料废水；TiO2负载；模板剂；介孔材料；吸附；光催化 Abstract Wastewater of industrial dyestuff has the defect of complex composition, high color and brings some refractory material which has serious threat to environment and human health. However, the adsorption material for dye still has the disadvantage of regeneration and secondary pollution. Fortunately, the mesoporous materials can be used in industrial wastewater purification due to its abundant pore channel and large specific surface area. TiO2 has strong light catalytic properties of organic compounds, the degradation of the selective low and makes completely mineralized, no secondary pollution. The preparation of TiO2-loaded mesoporous adsorbent has successfully been performed by hydrothermal method. The structures and properties were characterized based on the analysis of the nitrogen isotherms, the XRD patterns, the FTIR spectra, and electron microscopy. The mesoporous adsorbent was employed in adsorption and photocatalysis of Rhodamine B and Methylene Blue. The results show that the adsorption capacity to Rhodamine B can be reached 20.54mg/g in only 10 minutes and to Methylene Blue it can be reached 23.79mg/g in only 20min. And photocatalytic degradation of the dye can be reached above 99% in 50 minutes for Rhodamine B and 25 minutes for Methylene Blue. Keywords: wastewater; TiO2 loading; template agent; mesoporous materials; adsorption; photocatalytic 目 录 TOC \o 1-3 \h \z \u HYPERLINK \l _Toc294984555 摘 要 PAGEREF _Toc294984555 \h I HYPERLINK \l _Toc294984556 Abstract PAGEREF _Toc294984556 \h II HYPER