共存污染物对阿特拉津在天然沉积物上吸附的影响-表面活性剂.PDFVIP

第 24 卷第 4 期 环 　境 　科 　学 　学 　报 Vol. 24 ,No. 4 2004 年 7 月 ACTA SCIENTIAE CIRCUMSTANTIAE July ,2004 ( ) 文章编号 2004 　　　中图分类号:X131 　　　文献标识码 :A 共存污染物对阿特拉津在天然沉积物上吸附的 影响 ( ) 陶庆会 , 汤鸿霄　 中国科学院生态环境研究中心环境水质学国家重点实验室,北京　100085 摘要 :实验研究了重金属和表面活性剂对阿特拉津在沉积物上吸附的影响. 结果表明 ,Cu2 + 和 Cd2 + 在低浓度时对阿特拉津 吸附无影响或降低其吸附 ,高浓度时则能明显或轻微促进其吸附. 在实验浓度范围内 ,与对照相比 ,表面活性剂十二烷基苯 ( ) ( ) ( - 1 ) 磺酸钠 SDBS 和十六烷基三甲基溴化铵 CTAB 抑制阿特拉津的吸附 ,而 Span20 则在低浓度时 ≤1 mg ·L 抑制阿特拉 ( - 1 ) 津的吸附 ,高浓度时 1 mg ·L 促进其吸附. 关键词 :阿特拉津; 重金属 ; 表面活性剂 ; 沉积物 ; 吸附 Influences of coexisting pollutants on the sorption of atrazine by natural sediment ( TAO Qinghui , TANG Hongxiao 　 State Key Laboratory of Environmental Aquatic Chemistry , Research Center for Eco Environmental Science , Chinese Academy of Sciences , Beijing 　100085) Abstract :In this study , a series of experiments were carried out to determine the influences of heavy metals and surfactants on the sorption of 2 + 2 + atrazine in sediment. The results showed that Cu did not affect the adsorption of atrazine while Cd decreased atrazine adsorption at lower 2 + 2 + concentrations. However at higher concentrations , Cu could greatly and Cd could slightly enhance the adsorptive capacity of atrazine , respectively. Over the range of surfactant concentrations examined , SDB