线性扫描极谱法检测白酒中邻苯二甲酸二甲酯.PDFVIP

※安全检测 食品科学 2015, Vol.36, No.08 211 线性扫描极谱法检测白酒中邻苯二甲酸二甲酯 * 高志越，薛 菲，高娅玲，陈 文 ，张翼民 （成都理工大学材料与化学化工学院，四川成都 610059 ） 摘  要：邻苯二甲酸二甲酯在4.5 mL 柠檬酸-Na2HPO4 （pH 7.12 ）缓冲溶液、2.0 mL 0.5 mol/L KCl 溶液、 6.0 mL 5.0 ×10－4 mol/L十二烷基硫酸钠底液中，于起始电位－0.30 V （饱和甘汞电极（saturated calomel electrode， E I ” SCE ））、峰电位（ ）－1.18 V （vs. SCE ）左右处产生一个灵敏的极谱还原波，该波的二阶导数峰电流（ ）与 p p 邻苯二甲酸二甲酯的质量浓度在5.913～177.4 µg/mL范围内呈良好的线性关系，检出限为0.58 µg/mL 。本法操作简 单、快速、准确，用于白酒中邻苯二甲酸二甲酯的测定，结果令人满意。 关键词：塑化剂；邻苯二甲酸二甲酯；极谱法；白酒 Determination of Dimethy Phthalate in Chinese Liquors by Linear Sweep Polarography * GAO Zhiyue, XUE Fei, GAO Yaling, CHEN Wen , ZHANG Yimin (College of Materials and Chemistry and Chemical Engineering, Chengdu University of Technology, Chengdu 610059, China) Abstract: A method for the determination of dimethyl phthalate in Chinese liquors by linear sweep polarography was established. The initial potential was -0.30 V ( vs. saturated calomel electrode (SCE) ) in the supporting solution consisting of of 4.5 mL of citrate-Na HPO buffer solution (pH 7.12) with sequential addition of 2.0 mL of 0.5 mol/L KCl and 6.0 mL 2 4 -4 ’’ ×