添加剂对蜈蚣草燃烧过程中砷迁移规律的影响.PDFVIP

中国环境科学 2018,38(2) ：643~650 China Environmental Science 添加剂对蜈蚣草燃烧过程中砷迁移规律的影响 * 李小乐,段伦博 ,余志健,颜 勇,赵长遂 (东南大学能源与环境学院能源热转换及其过程教育部重点实验室, 江 南京 210096) 摘要：蜈蚣草是砷(As)的超富集植物,为了研究 CaO、MgO 以及白云石对蜈蚣草燃烧过程中砷迁移规律和赋存形态的影响,利用管式炉装 置进行了一系列的实验,结果表明:3 种添加剂在 400~700 ℃温度区间固砷效果明显,MgO 的固砷效果最佳、CaO 其次、白云石最差.CaO 和 MgO 的最佳固砷温度为 500℃,最佳固砷效率分别为 17%和 14%; 白云石的最佳固砷温度为 700 ℃,最佳固砷效率为 10%.燃烧温度在 400~500 ℃时,掺混添加剂会使底灰中可溶砷的比例提高约 5%,这是由于温度较低时,这 3 种添加剂主要是通过物理吸附对砷进行固定;而当 温度超过 800℃时,底灰中可溶砷的比例降低约 10%,这是由于添加剂影响了底灰对砷的自固定,减少了可溶性砷化合物的形成.当温度低于 700℃时,掺混添加剂会使底灰中出现少量 As3+. 关键词：添加剂；蜈蚣草；燃烧；砷挥发率；可溶砷 中图分类号：X131 文献标识码：A 文章编号：1000-6923(2018)02-0643-08 The Influence of different additives on the transformation behavior of arsenic during the combustion of the P. * vittata. LI Xiao-le, DUAN Lun-bo , YU Zhi-jian, YAN Yong, ZHAO Chang-sui (Key Laboratory of Energy Thermal Conversion and Control, Ministry of Education, School of Energy and Environment, Southeast University, Nanjing 210096, China). China Environmental Science, 2018,38(2)：643~650 Abstract ：P . vittata is one of the hyperaccumulators of arsenic(As),a series of experiments were conducted in a horizontal tube furnace to investigate the influence of CaO, MgO and dolomite on the transformation behavior of As during the combustion of P. vittata . The results showed that the As retention of CaO, MgO and dolomite was efficient during 400~700 ℃,and the MgO performed best, followed by CaO and dolomite. The most proper temperature of As retention of CaO and MgO was 500℃, while that was 700℃ for dolomite. It was found that the low temperature would promote the formation of soluble As when the ad