碱金属离子改性对纳米HZSM鄄5沸石丁烯裂解催化性能的影响.PDFVIP

第39卷 第6期 燃摇 料摇 化摇 学摇 学摇 报 Vol.39 No.6 2011年6月 Journal of Fuel Chemistry and Technology Jun. 2011 文章编号:0253鄄2409(2011)06鄄0449鄄06 碱金属离子改性对纳米HZSM鄄5 沸石丁烯裂解催化性能的影响 徐瑞芳,刘家旭,梁翠翠, 贾文浩,李福芬,郭洪臣 ( 大连理工大学 化工学院催化化学与工程系精细化工国家重点实验室,辽宁 大连摇 116012) 摘摇 要:利用NH 鄄TPD表征和小型固定床反应评价研究了不同碱金属离子浸渍改性对纳米HZSM鄄5沸石的酸度及混合碳四 3 液化气中丁烯催化裂解性能的影响。 结果表明,尽管锂、钠、钾改性在达到最佳乙烯和丙烯选择性时对应的负载量不同,但其 最佳乙烯和丙烯选择性为50% ~60%。 碱金属离子改性催化剂在连续运转过程中其催化活性缓慢下降,但乙烯和丙烯选择 性没有明显增加。 丁烯异构体在催化剂上转化率由大到小的顺序为:丁烯鄄1 反丁烯鄄2 顺丁烯鄄2 异丁烯。 关键词:碱金属离子;纳米HZSM鄄5 沸石;丁烯;催化裂解;丙烯;碳四液化气 中图分类号:O643摇 摇 文献标识码:A Effect of alkali metal ion modification on the catalytic performance of nano鄄HZSM鄄5 zeolite in butene cracking XU Rui鄄fang,LIU Jia鄄xu,LIANG Cui鄄cui,JIA Wen鄄hao,LI Fu鄄fen,GUO Hong鄄chen (State Key Laboratory of Fine Chemicals, Department of Catalytic Chemistry and Engineering,Dalian University of Technology,Dalian摇 116012,China) Abstract:Nano鄄HZSM鄄5 was modified by different alkali metal ions; the effect of the modification on its acidity and catalytic performance in butene cracking was investigated by using NH 鄄TPD characterization and 3 catalytic evaluation in a small fixed鄄bed reactor. The results indicated that although the catalysts modified with variousions of Li,Na and K are different in their metal loading required to achieve the highest selectivity to ethylene and propylene,the best selectivity value obtained over all these modified catalystsislocated in 50% ~ 60%. The activity of the alkali modified catalysts decreases slowly with the extension of the reaction time on stream;however,the selectivity to ethylene and propylene does not increase accordingly. The conversions of different