《热处理对镁碳质耐火材料中碳的纳米化研究的影响》-毕业论文.docVIP

PAGE 摘 要 　　 碳是镁碳砖的重要组份，它是镁碳砖获得优良性能的关键成份。在镁碳砖的原料中，碳的主要来源是鳞片石墨及酚醛树脂。所以为了提高镁碳砖的性能，一般都致力于研究石墨和结合剂的性能对镁碳砖的影响。当今时代，纳米技术深入到了各个领域，不妨将其引入到镁碳砖中，测试镁碳砖性能是否变化。由于镍在一定的条件下可以催化含碳气体生成碳纳米纤维，故本实验采用硝酸镍为催化剂，经一定的工序生产出镁碳砖后，对其生成碳纳米纤维的可能性进行了研究，并对比了加入催化剂后制得的镁碳砖性能的变化。对不同热处理温度制得的镁碳砖性能变化进行了对比。 实验结果表明，当引入一定量的催化剂后，可以在镁碳砖中可以生长出碳纳米纤维。而且，碳纳米纤维的生长情况还和热处理的温度有关，当处理温度为1100℃时，碳纳米纤维的生长情况较好。 关键字：碳纳米纤维； 催化剂； 热处理； 镁碳砖 Abstract Carbon is an important component for MgO-C Bricks, it is the excellent performance of MgO-C Bricks to obtain a key ingredient. In the magnesia raw materials, the major source of carbon is graphite and phenolic resin. Therefore, in order to improve the performance of MgO-C Bricks, generally dedicated to the research of Graphite and binders’ impact of performance on the MgO-C Bricks. The present era, nano-technology down to the fields, it may be introduced it into the MgO-C brick and test whether the performance changes. Because nickel catalyst under certain conditions can produce carbon nanofibers in carbon gases, so the present study, we use Ni(NO3)2 as catalyst, Through certain processes to produce MgO-C brick, Study the possibility formation of carbon nanofibers, Were compared performance changes with the different heat treatment for MgO-C Bricks. The experimental results show that when introducing a certain amount of catalyst, carbon nanotubes can be grown in the MgO-C Bricks. Moreover, the growth of carbon nanotubes also due to the temperature of the heat treatment, the best growth temperature of carbon nanotubes is 1100 ℃. Key words: Carbon nanofibers; Catalyst; Heat treatment; MgO-C Bricks 目 录 TOC \o 1-3 \u 1 文献综述 PAGEREF _Toc295728712 \h 1 1.1 前言 PAGEREF _Toc295728713 \h 1 1.2 镁碳砖的特点 PAGEREF _Toc295728714 \h 1 1.3镁碳砖的生产工艺 PAGEREF _Toc295728715 \h 2 1.4 镁碳砖生产所用原料 PAGEREF _Toc295728716 \h 2 1.4.1 镁砂 PAGEREF _Toc295728717 \h 2 1.4.2 石墨 PAGEREF _Toc295728718 \h 3 1.4.3 结合剂 PAGEREF _Toc295728719 \h 3 1.4.4 金属添加剂 PAGEREF _Toc295728720 \h 4 1.5 镁碳砖中的碳 PAGEREF _Toc29