白云石灰浆碳化反应动力学研究-河北科技大学学报.PDFVIP

26 2 V ol . 26, No . 2 2005 6 J ournal o f Hebei U niv ersity of Science and T echnolog y J une 2005 2005) 020 11806 1 2 1 3 刘宝树 , 乔满辉, 胡庆福 , 翟学良 ( 1. 河北科技大学化学与制药工程学院, 河北石家庄 050018; 2 . 石家庄制药集团中诺药业( 石家 庄) 有限公司, 河北石家庄 05005 1; 3. 河北师范大学实验中心, 河北石家庄 050016) 通 对碳化反应速率影响因素的研究, 计算出反应的活化能, 推断出了碳化反应的机 理 Ca( O H ) 2 碳化属扩散控制 程, 而M g( O H ) 2 碳化则为化学反应控制 程, 并给出碳化反 应的双膜理论模型对确定最佳碳化反应条件, 实现钙镁分离具有理论指导意义 白云石; 碳化法; 反应动力学; 反应机理; 反应模型 O 643 . 12 A K inetics of t he carbonat ion of dolom it e slurr y 1 2 1 3 L IU Baoshu , Q IA O M anhui , H U Q ingfu , ZH A I Xu eliang ( 1. College o f Chem ical and Ph arm aceutical Eng ineer ing, Hebei U niv ersity of Science and T echnolog y, Shij iazhu ang H ebei 050018, China; 2. Zhongnuo Ph arm aceut ical( Shij iazhu ang ) Co. , L td , Shijiazhuang P har m aceutical G ro up , Shijiazhu ang H ebei 05005 1, China; 3. Labr ator y, H ebei N orm a l U niver sity, Shijiazhu ang Hebei 050016 , China) Abstract: T he f acto rs aff ecting the r eaction rate of the car bo nation of dolo m ite slur ry w er e st udied , and the activatio n ener gy of the reaction s w as w o rked out . O n the basis of the abo ve co nclusio n, the r eaction m ech anism w as dedu ced prelim inarily , th at is, the car bo nat ion o f Ca( O H) 2 is a pr oceso of diffu sion co nt ro l w hile the car bo nation o f M g ( O H) 2 is a pr oceso o f chem ical reac t ion co nt ro l. T he theo retical car bonatio n r eaction mo del w as established, and it is signif icant in determ ining the optimum co ndi t ion f or ca rbonation r eaction an