CC复合材料表面改性对SiC涂层抗氧化性能的影响EffectofCarbon.PDFVIP

July 2013, Volume 3, Issue 3, PP. 26-30 Scientific Journal of Microelectronics C/C 复合材料表面改性对SiC 涂层抗氧化性能的影响 1,2 1 2 2 1, 2 李丙菊 ，褚胜林 ，李军 ，谭周建 ，廖寄乔 1. 中南大学 粉末冶金国家重点实验室，长沙 410083 2. 湖南金博复合材料科技有限公司，益阳 413000 摘 要：采用化学气相沉积法（chemical vapor deposition, CVD）在碳/碳（C/C）复合材料表面原位生长CNTs、SiCw 制备CNT-SiC 涂层、SiCw-SiC 涂层；利用SEM 分析涂层的微观形貌，研究C/C 复合材料表面改性对SiC 涂层抗氧化性能的影响。结果表 明：原位生长的的CNTs 和SiCw 起到了连接基体与SiC 之间的桥梁作用，有效地抑制了涂层裂纹的产生，提高了涂层抗氧化 能力和抗热震性能。经 1100℃恒温氧化 10 小时后，CNT-SiC 涂层和 SiCw-SiC 涂层的质量损失率是 34.36%、9.78% ；经 （1100℃←→ 室温）热震循环15 次后，两种涂层质量损失率为30.37%、6.72% 。 关键词：C/C 复合材料；化学气相沉积；抗氧化涂层；表面改性 Effect of Carbon/Carbon Composites Surface Modifi- cation on Anti-oxidation Properties of SiC Coating 1, 2 1 2 2 *1, 2 Bingju Li , Shenglin Chu , Jun Li , Zhoujian Tan , Jiqiao Liao 1. State Key Laboratory of Powder Metallurgy, Central South University, Changsha, China, 410083 2. Hunan Kingbo Carbon-carbon Composites Co., LTD., Yiyang, China 413000 Email: liaojiqiao@126.com Abstract: The CNT-SiC coating and SiCw-SiC coating were prepared by CVD method with CNTs and SiCw in-suit growth on car- bon/carbon(C/C) composites surface first. The surface micromorphology of the coating was characterized by SEM techniques. The SiC coating anti-oxidation property of the surface modification were investigated. The results show that the CNTs and SiCw connect the body and SiC coating, and can prevent cracks effectively. Even in the case of surface modification, the anti-oxidation property and the thermal shock resistance of coating are increase all. After oxidation at 11