《含糠醛结构单元非线性光学材料合成研究》-毕业论文.doc

abstract 摘 要 PAGE II PAGE I 摘 要 非线性光学材料是集成光学器件的关键材料。与无机非线性光学材料相比，有机材料以其更好的光学、热学和力学性能而受到研究人员的广泛重视。本文合成了一种含有糠醛结构单元的非线性光学材料：2-二氰亚甲基-3-氰基-4-[2-(4-二甲氨基-苯乙烯基-呋喃基-5)-乙烯基]-5,5-二甲基-2,5-二氢呋喃。热性能测试表明其热分解温度达到280℃，耐热性良好，可以达到器件制备的要求。在DFT-B3LYP/6-31G基组下计算得到分子的μβ0值为13633×10-48esu；通过溶致变色法测试得到该分子的μgβCT（1064nm）为24898×10-48esu，计算和测试结果均表明此类材料具有良好的非线性光学特性。 关键词：非线性光学材料，糠醛，合成，溶致变色法 ABSTRACT 目 录 PAGE III ABSTRACT Nonlinear optical (NLO) materials are the key integrated optics component materials. Compared to the inorganic NLO materials, organic counterparts have been attracted much attention due to their better properties on photics, thermotics and mechanics. A NLO chromophore containing the furfural unit is synthesized, which names 2-dicyanomethylene-3-cyano-4-{2-[(4-dimethylamino-styreneyl)-furyl-5]-vinyl} -5,5-dimethyl-2,5-dihydrofuran. Based on TGA and DSC curves, the thermal decomposition temperature of this chromophore is 280℃. Thus, the material shows good heat resistance, which is according with the component’s request. The μβ0 value is calculated to be 13633×10-48esu with DFT-B3LYP/6-31G method. The value of μgβCT（1064nm）measured by solvatochromism is 24898×10-48esu. The calculated and observed value indicates that the organic nonlinear optical materials with this structure show excellent non-linear properties. Key words: NLO material, furfural, synthesize, solvatochromism 目 录 目 录 TOC \o 1-4 \h \z \u HYPERLINK \l _Toc233139571 第1章 引言 PAGEREF _Toc233139571 \h 1 HYPERLINK \l _Toc233139572 1.1非线性光学材料的研究背景 PAGEREF _Toc233139572 \h 1 HYPERLINK \l _Toc233139573 1.2 本文的设计思路 PAGEREF _Toc233139573 \h 2 HYPERLINK \l _Toc233139574 1.3课题核心任务和主要工作 PAGEREF _Toc233139574 \h 2 HYPERLINK \l _Toc233139575 第2章 非线性光学材料概述 PAGEREF _Toc233139575 \h 3 HYPERLINK \l _Toc233139576 2.1非线性光学基本原理 PAGEREF _Toc233139576 \h 3 HYPERLINK \l _Toc233139577 2.2非线性光学的发展 PAGEREF _Toc233139577 \h 4 HYPERLINK \l _Toc233139578 2.2.1非线性光学材料的发展史 PAGEREF _Toc233139578 \h 4 HYPERLINK \l _Toc233139579 2.2.