基于多电子反应的新型电极材料NovelElectrodeMaterialsBasedon.PPT

* 基于多电子反应的新型电极材料 Novel Electrode Materials Based on the Concept Multi-Electron Reactions 吴 川 吴 锋 WU Chuan WU Feng 北京理工大学化工与环境学院 School of Chemical Engineering and the Environment Beijing Institute of Technology Beijing 100081, China E-mail: chuanwu@bit.edu.cn 新型二次电池及相关能源材料的基础研究 Novel Secondary Batteries and Relative Energy Materials Contract No. 2009CB220100 (2009-2013) 绿色二次电池新体系相关基础研究 Fundamental Research on New Green Secondary Batteries Contract No. 2002CB211800 (2002-2008) 首席科学家：吴锋 Chief Scientist: WU Feng 国家重点基础研究发展计划（973计划，科技部资助） National Basic Research Development Program of China (973 program, supported by the MOST) 多电子反应与多电子材料 Multi-electron reaction Multi-electron material Our Team 国家高技术绿色材料发展中心 高比能电池的需求 The Demands for High Energy Density Batteries (HEDB) ED ? Energy density, either per unit of weight (Wh/kg) or per unit of volume (Wh/L) n ? the number of electrons transferred per mole of reactants in a cell reaction E0 ? the electromotive force (emf) of the cell reaction ΣMi ? the sum of the formula weights of active materials being transformed in the cell reaction (redox drivers) ED ? 质量能量密度 (Wh/kg) 或 体积能量密度(Wh/L) n ? 每摩尔反应物的电子转移数 E0 ? 反应电动势 ΣMi ? 活性物总质量 Energy Environ. Sci. 3 (2010) 174–189 C ? the theoretical capacity of the electrode material F ? the Faraday constant n ? the total electric charge passed through the electrode M ? the molar mass of the electrode material 高容量电极材料 High Capacity Electrode Materials for HEDB The Faraday’s Law Electrochem. Commun. 11 (2009) 2173, Electrochem. Commun. 11 (2009) 145 1摩尔这种硼化物在特定电化学反应中能够转移的电子数大于1摩尔，因而被视为多电子材料，并具有实现超高比容量的潜力。 “……one mole of such borides can transfer more than one mole of electrons through specific electrochemical reactions, such that they can be regarded as multi-electron materials and thus have the potential to achieve extremely high-capacity……” 多电子电极材料的典型实例：金属硼化物 Typical Examples of Multi-electron Materials: Metal Borides Energy Environ. Sci. 3 (2010) 174–1