《松脂制备聚合松香工艺条件的研究》-毕业论文.docVIP

PAGE w 松脂制备聚合松香工艺条件的研究 摘 要 以广西特色资源松脂为原料、200#油为溶剂、冰醋酸、AlCl3和ZnCl2为催化剂进行松脂异构和聚合反应工艺条件研究。在超声波辅助条件下，考察了脂油质量比、催化剂种类及用量、反应速度和时间对松脂异构反应的影响。结果表明松脂异构适宜工艺条件为：脂油质量比为1：0.8，催化剂冰醋酸用量为0.042ml/g松脂，反应温度为55℃，反应时间60min。以异构后的松脂为原料，采用单因素法考察了用松脂直接制备聚合松香过程脂油质量比、催化剂用量、反应温度、反应时间对聚合反应的影响，确定最适宜聚合工艺条件为：脂油质量比1：1.5、反应温度80℃、反应时间6小时、催化剂AlCl3和ZnCl2各3%，并可得到最高得率为95.6%和软化点为105℃的聚合松香。与原有松脂制备聚合松香工艺相比，软化点从88℃提高到了105℃。克服了传统工艺用优质松香为原料成本大的缺点，为松香聚合工业开辟一条新途径。 关键词：松脂 聚合松香 异构 工艺条件 STUDY ON PERPARATION CONDITIONS OF POLYMERIAED ROSIN WITH RESIN AS RAW ABSTRACT Featured Resources of Guangxi as raw material resin, 200 # oil as solvent, acetic acid, AlCl3 and ZnCl2 as the catalyst preparation of polymerized rosin resin heterogeneous and technological conditions. In ultrasonic conditions, investigated fat mass ratio, catalyst type and amount of reaction rate and time on the pine heterogeneous reaction. The results show that the optimum conditions for the heterogeneous resin: fat mass ratio of 1:0.8, catalyst amount of acetic acid 0.042ml / g resin, the reaction temperature is 55 ℃, reaction time of 60min. After the resin to heterogeneous raw materials, were investigated by single-factor method using polymerized rosin resin preparation process of the direct fat mass ratio, catalyst amount, reaction temperature, reaction time on polymerization reaction, to determine the most suitable for the Polymerization Process Conditions: fat mass ratio of 1:1.5, reaction temperature 80 ℃, reaction time 6 hours, the catalyst AlCl3 and ZnCl2 (rosin mass basis) and 3%, and the highest yield was 95.6% and the softening point of 105 ℃ of polymerized rosin. Preparation of polymerized rosin resin with existing technology than the softening point increased from 88 ℃ to 105 ℃. Overcome the traditional craft with high-quality rosin as raw material costs and a disadvantage, for the rosin polymer industry to open up a new way. Keywords：resin polymerized rosin isomerism technological conditions 目录 TOC \o 1-3 \h \z \u HYPERLINK \