《流动注射双安培法在线测定扑热息痛的研究》-毕业论文.docVIP

精品 精品 精品 流动注射双安培法在线测定 的研究中 流动注射双安培法在线测定 的研究 中 扑热息痛的研究 扑热息痛的研究 Flow injection biamperometric determination of paracetamol on Flow injection biamperometric determination of paracetamol on paracetamol on paracetamol on 作者姓名 作者姓名 化 学专业名称 化 学 专业名称 理 学学科门类 理 学 学科门类 成绩评定提交论文日期指导教师 成绩评定 提交论文日期 指导教师 2012年5月 精品 摘 要 利用不可逆电对的双安培法玉检测原理，建立了流动注射双安培直接检测扑热息痛的电化学新方法。使用经过恒电位预阳极化处理的双铂电极，通过耦合扑热息痛在一支电极上的氧化和氧化铂在另一支电极上的还原两个不可逆电极过程，构成流动注射双安培检测体系。在外加电位差为0 V 时, 扑热息痛的氧化电流与其浓度在4.0×10-4～8.0×10-4 mol/L范围内呈线性关系, 检出限为5. 0 × 10- 7 mol/ L, 连续20 次测定扑热息痛5.0×10-5 mol/L , 电流值RSD 为3.30%. 关键词：扑热息痛；流动注射分析；双安培法;不可逆电对 Abstract A novel flow-injection electrochemical method for direct determination of paracetamol was developed in this paper based on the biamperometric detection by an irreversible couple system. The applied voltage between two Pt electrodes ,in which the eletrocatalytic oxidation of paracetamol occurred at one platinum electrode,coupled with the reduction of PtO at another Pt electrode. under the applied potential differenceof 0 V, the linearity between current and phenol concentration was obtained over the range of4.0×10-4～8.0×10-4 mol/L with the detection limit 5. 0 × 10- 7mol/L. The relative standard derivation of 3.30% wasobtained for 30 successive determinations of 5. 0×10- 5mol/ L phenol.The method has been successfully applied to the determination of paracetamol in real samples with satisfactory results. Key words: paracetamol; flow injection analysis; biamperometric; irreversible couple 精品 精品 目 录 TOC \o 1-3 \h \z \u HYPERLINK \l _Toc264833954 摘 要 PAGEREF _Toc264833954 \h I HYPERLINK \l _Toc264833955 前 言 PAGEREF _Toc264833955 \h 1 HYPERLINK \l _Toc264833956 1 文献综述 PAGEREF _Toc264833956 \h 2 HYPERLINK \l _Toc264833957 1.1 扑热息痛的发现历史及性质和应用 PAGEREF _Toc264833957 \h 2 HYPERLINK \l _Toc264833958 1.1.1发现历史 PAGEREF _Toc264833958 \h 2 HYPERLINK \l _Toc264833959 1.1.2 性质和应用 2 HYPERLI