《在碱热处理条件下镁表面产生氧化镁膜层实验及氧化镁膜层的组织结构、性能研究》-毕业论文.docVIP

PAGE 摘 要 论文探讨了在碱热处理条件下镁表面产生氧化镁膜层的过程，并对氧化镁膜层的组织结构、性能进行了研究。讨论了碱处理温度、碱处理时间和碱液pH值对膜层沉积效果的影响；本文重点比较了几种不同处理工艺所产生的膜层耐蚀性能及试样在浸泡过程中SBF溶液的pH值的改变情况；观察了不同处理工艺表面的膜层形貌；并对试样表面进行能谱分析，得出了最佳处理工艺。 研究结果表明：通过对纯镁试样进行碱处理、碱热处理及碱处理后电化学沉积等过程，得到了不同成分的膜层：碱处理试样表面膜层为碳酸镁；碱热处理试样表面膜层为氧化镁；碱处理后电化学沉积试样表面膜层为钙磷层。当碱处理温度为60 ℃，碱溶液为SNSM溶液，保温时间24 h，碱处理后在773 K温度下保温10 h热处理，可以获得耐蚀性能最佳的膜层，膜层致密、均匀，与基体结合牢固。耐蚀性能实验结果表明，在SBF溶液中浸泡，经碱热处理的试样腐蚀失重和腐蚀速率远低于未经任何表面处理的纯镁。后者的腐蚀速率一直维持在很高的数值，而前者的腐蚀速率在浸泡约120 h后才明显增加；碱处理和碱处理后电化学沉积的试样腐蚀速率都有所减小，经碱热处理的试样在模拟体液中的耐蚀性能最好。 关键词：镁；碱热处理；模拟体液；耐蚀性能 Abstract The thesis discussed the alkali treatment conditions in the surface layer of magnesium magnesium membrane, and the process of magnesium oxide film structure and properties were studied. Discuss the alkali treatment processing time and temperature, pH value of lye effects of membrane layer deposition, This paper compares the different process produces coating corrosion resistance and sample SBF solution soaking in the process of changing the pH value; Observe the different treatment process of surface coating morphology, And on the surface energy spectrum analysis, the optimal process. Research results show that based on pure magnesium specimen alkali treatment, alkali treatment and electrochemical deposition etc after alkali treatment process, the composition of membrane layer: alkali treatment for magnesium carbonate samples surface coatings, Alkali treatment for magnesium oxide coating specimen surface, The electrochemical deposition sample after alkali treatment for calcium phosphate film surface layer. When the temperature of alkali treatment for 60 degrees, the alkali solution for SNSM solution, holding time 24 h after alkali treatment in 773 K temperature heat insulation, can get 10 h corrosion resistance performance of the best film coating, dense, uniform, and with solid matrix. Corrosion resistance experiment results show that, in SBF solution soaking by alkali treatment, the sample corrosion and corrosion rate are far below z