大颗粒草酸钕前驱体的制备及热分解研究-冶金工程专业论文.docx

reactant acidity is 2.5mol/L and the aging temperature is 45℃. The results of thermal decomposition of neodymium oxide and kinetics analysis show that the TG/DTG/DTA curves move to the high-temperature sides with the increasing of the heating rate. The higher the heating rate, the higher corresponding temperature to reach the same weight loss rate, the obviously higher weight loss rate of DTG curve with the maximum heating rate, the larger peak area of DTA curve and the higher absolute value of enthalpy under the same temperature. The activation energy values of anhydrous neodymium oxalate decomposed to Nd2O2CO3 is 130.10~187.8kJ/mol and the reaction is in accordance with the three-dimensional diffusion model. The activation energy values of Nd2O2CO3 decomposed to Nd2O3 is 57.4~81.83kJ/mol. Key word：Nd2O3；large particle size；P507-N235；stripping solution；kinetics 目 录 摘 要 .....................................................................................................................................I Abstract ..................................................................................................................................... II HYPERLINK \l _bookmark0 第一章 文献综述 .................................................................................................................... 1 HYPERLINK \l _bookmark1 1.1 氧化钕的性质及应用 .................................................................................................. 1 HYPERLINK \l _bookmark2 1.2 大颗粒稀土化合物的研究现状 .................................................................................. 1 HYPERLINK \l _bookmark3 1.2.1 大颗粒钕化合物制备研究进展 ........................................................................ 2 HYPERLINK \l _bookmark4 1.2.2 其他大颗粒稀土化合物制备研究进展 ............................................................ 3 HYPERLINK \l _bookmark5 1.3 沉淀形核及晶核生长机理研究 .................................................................................. 5 HYPERLINK \l _bookmark6 1.3.1 沉淀形核 ................