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正丁醛与氯原子反应的动力学和机理研究-环境科学学报
25 2 Vol.25,No. 2
2005 2 ACTA SCIENTIAE CIRCUMSTANTIAE Feb., 2005
, , . [J] . , 2005, 25( 2) : 143- 147
WU Hai, ZHANGYi,MU Yujing. inetics and mechanism of the reaction for nbutyraldehydewith Cl atoms[J]. Acta Scientiae Circumstantiae, 2005, 25( 2) : 143
- 147
1, 2 1 1
吴 海 , 张 逸, 牟玉静
1 , 100085; 2, 100013
: , , k 2 = ( 119
8 3 - 1 - 1
010) 10 m !mol !s ; : CO CO .
2
, ∀ CHO 44%, 25%, 20% 11% .
: ; ; ;
:2005) :X8302 : A
Kinetics and mechanism of the reaction for nbutyraldehyde with Cl atoms
1, 2 1 1
WU Hai ,ZHANG Yi ,MU Yujing
1Research Center for EcoEnvironmental Sciences, Chinese Academy of Sciences, Beijing 100085; 2Research Center for Certified Reference Center, Beijing
100013
Abstract: Thephotooxidation of nbutyraldehyde initiatedbyCl atomswas studied at room temperatureand1atm. by usingGCFID andGCMS. The rate constant
8 3 - 1 - 1
for thereaction of nbutyraldehydewith Cl atomswhichwas obtained byrelativemethodwas ( 119 010) 10 m !mol !s Themajor products of thereac
tion were propionaldehyde, acetaldehyde, COand CO . Being considered thesemajor products and their formationyields, thebranching ratios of Cl attacking at the
2
∀ CHO, and positions in nbutyradehydewere44%, 25%, 20% and 11%, respectively. Themechanism of thereaction was also discussed in detail.
Keywords:nbutyraldehyde; Cl atom; rate constant; photooxidation
.
, Cl
, , ,
. Cl .
[ 1, 2]
. ,
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