水果中菊酯类农药残留的快速检测分析-食品安全质量检测学报.PDF

5 6 Vol. 5 No. 6 2014 6 Journal of Food Safety and Quality Jun. , 2014 * 王翠芬, 高 雪, 刘 萍, 齐雅薇, 刘晓慧 , 颜 红 (, 071001) 摘 要: 目的 , 方法 CleanertPC/NH2 SPE , GC , 结果 4 0.008~0.4 μg/mL , , 0.99903 0.99993 , 0.002 mg/kg , 91.43%~100.94%, 5.45%~8.20%, 0.002 mg/kg结论 关键词: ; ; ; Fast determination of pyrethriod pesticide residues in fruits * WANG Cui-Fen, GAO Xue, LIU Ping, QI Ya-Wei, LIU Xiao-Hui , YAN Hong (Baoding Entry-Exit Inspection and Quarantine Bureau, Baoding 071001, China) ABSTRACT: Objective A method for determination of pyrethriod pesticide residues in fruits was devel- oped by gas chromatography (GC) to provide a reliable test for the future work. Methods After homogeniza- tion of the fruit samples, the pesticide residues were extracted by acetoneitrile, cleaned up by a CleanertPC/NH2 SPE column and then determined by GC using the external standard method. Results The calibration curve showed a good linearity in the range of 0.008~0.4 μg/mL, and the correlation coefficient was 0.99903~0.99993 for herbicides. The recovery rate of labeled samples was 91.43%~100.94%, with the relative standard devia- tions were 5.45%~8.20%, and the detection limit was 0.002 mg/kg. Conclusion This method is simple, rapid, and has high precision and accuracy. KEY WORDS: gas chroma