芳烃抽提工艺的计算机模拟-化学工程专业论文.docxVIP

1II 1II 摘要 芳烧是石油化学工业的重要的基础原料，而芳烛的主要生产工艺为芳烧抽 蝇，目前石油芳烧已经成为芳烧的主要来源。随着催化重整和蒸汽裂解反应深度 的不断提高，石油芳怪中的非芳烧含量明显减少。因此抽提精馆越来越多的作为 劳烧抽提的主要工艺。 本文通过实验测定了环丁枫唰芳煌非芳煌的部分液液 衡数据。通过环丁枫 芳烧唰非芳:怪三元相阁的绘制得出三种物系为单一液相时的混合比例。同时通过 数掘回归得出丁环丁枫.芳烧 \f (如 二元交互参数@另外采用过程模拟软件 PRO/lI 对某厂的以环丁枫为榕剂的芳烧 抽提工艺(主要是抽提精馆工艺)进行各个单塔模拟以及全流程模拟。在抽提精 ‘ 惰的模拟过程中在控制榕剂回收踏踏底温度的同时又能保证芳烧特别是混合工 甲笨的凹收事以及纯度，对原有的劳怪抽提工艺进行改进，在溶剂回收塔底通入 …部分汽提水蒸气用于提高二甲苯的收率和纯度。所得到的劳烧纯度符合国家质 量要求。在模拟过程中对于抽提精惰塔以及溶剂回收塔各个操作参数的选择做出 了详细得说明，找出了芳烧抽提工艺中提高纯度和收率以及降低能耗的一些规 律。 利用本文的模拟结果，可以为罔内芳怪抽提工艺特别是抽提精馈工艺的改 进、扩大规模提供一定的理论根据。同时本文的模拟结果可以作为特定原料的好 烧抽提工艺的工艺包。 关键词 z 芳烧分离抽提精锢 PRO/II 模拟 喃 喃喃.‘， IV IV ABSTRACT Aromatic is an important basic raw mat町ial in petroleum chemical industry，while the main production process for the aromatic 扭曲.e aromatic extraction. Now oil aromatic has become 胁 m句or source. As 也.e reaction level of c刷刷ic reforming and steam cracking increasing ，由e content of non- aromatic in oil aromatic is significantly reducing. As a result the extraction distillation process is becoming the major aromatlcs extractlon process. This paper 也rough the experiments det，创mined some sulfolane - aromatic - n，。如aromatic \， systems liquidliquid 叫uilibrium data. Through the triangular plo臼 drawing，we can {丸 determine the mixture of sulfolane aromatic - nonaromatic systems mixing ratio 咄咄也e system is a single phase. We also obtained the binary int町action parameters 1 of NRTL，and UNIQUAC models by 伽阳 regression. Using 由.e prl 侃s simulation software PRO / 11 simulated 由e aromatics extraction process (especially 也e extraction distillation process) bo由for single towers and 阳whole process. In ord时 to ensure the aromatics especially mixed xylenes yield and purity while control 也e recovery towers bottom 阳nperature，improved the process put some stripping steam into the bottom of 伽e solvent recovery tower. In this way improve the mixed xylenes yield and purity. It also made the purity accroad nationa1 standard. During the simulation， 1 detail创il1us