超重力络合铁法脱硫技术基础研究化学工程专业论文.docxVIP

中北大学学位论文 中北大学学位论文 其中溶液 pH 值为显著性影响因素。同时通过实验过程中一定量脱硫液随时间的衰减趋 势，结合硫容的相关公式，得出了所配脱硫液的实际硫容为 0.8g/L，比目前工业上各种 工艺的硫容大出 2 倍多，因而很大程度上减少了脱硫液的循环量，大大降低了生产过程 中的能耗。 最后对络合铁法脱硫工艺进行了初步的经济探讨与技术分析，通过各种工艺的经济 比较，进一步论证了该工艺在技术、经济方面的双重优势。超重力络合铁法脱硫由于脱 硫精度高、反应速度快且脱硫液循环量小、占地面积少，降低了基建费用和生产能耗， 为新生产线的建立提供方便，体现出了显著的经济优势。 关键词:H2S，脱硫，超重力技术，络合铁法，脱除效率，经济分析 Basic Research on High Gravity Desulfurization Technology by Complex Iron Abstract This thesis comprehensively reviews various methods and the latest researches of hydrogen sulfide gas purification. Various desulfurization technology is concluded from the perspective of the wet oxidation. The applicability, advantages and disadvantages are also described. Based on the full investigation of various processing methods, the author does a further study on the desulphurization mechanism of complex iron. The mechanism of desulphurization mechanism of complex iron and the combining mechanism of metal centers binding and amino carboxylic ligands are introduced. By summarizing the investigation and applications status of the desulfurization process by improved complex iron, the main technology embarrassment of desulfurization process by improved complex iron and its application prospect in the removal hydrogen sulfide in oil and gas field are analyzed in the thesis. Based on the improvement of the old solvent, the development of new technology and the optimization of operating conditions, this thesis takes H2S-air and self-desulfurization solution as the experimental system and puts forward the compound complex system desulfurization technology with sulfosalicylic acid as main complex agent, citric acid as promoter complex agent. In the condition of balanced efficiency with EDTA complex iron desulfurization, the cost of complex agents has been significantly reduced. At the same time, the compound complex system increases the stability of complex systems, and reduces the degradation of complex agents. It has obvious economic benefits. After the comp