《储氢合金Mm0.3Ml0.7Ni3.55Co0.75Mn0.4Al0.3的制备与性能研究》-毕业论文（设计）.doc

精品 PAGE 摘 要 采用感应熔炼的方法制备Mm0.3Ml0.7Ni3.55Co0.75Mn0.4Al0.3合金，并对合金进行机械球磨处理，球磨时间分别为6h，15h，40h和50h。球磨处理后的合金采用X射线衍射仪分析其晶体结构。采用最小二乘法和近似函数法分离晶粒和微应变在X衍射下产生的衍射峰，估算晶粒大小。结果表明，球磨6小时后，合金中出现纳米晶和多晶相。随着球磨时间的增加，合金的晶格参数和晶粒数目增加，晶粒尺寸减小。当球磨时间达到40小时以上，合金将部分转变为非晶组织。对合金电化学性能的测试结果表明，合金的最大储氢量随着球磨时间的延长而减小。球磨处理对合金的活化性能影响不大，但能明显改善合金的循环稳定性。经不同球磨时间处理后合金的循环稳定性均优于铸态合金，且随着球磨时间的延长，合金的循环稳定性提高。Mm0.3Ml0.7Ni3.55Co0.75Mn0.4Al0.3合金较适宜的球磨处理工艺为：球磨时间6h，处理后合金的最大放电容量为290mAh/g，合金经2次充放电循环即可活化，合金经60次充放电循环后的容量保持率为0.81。 关键词：储氢合金；机械球磨；相结构；电化学性能 Abstract The as-cast alloy with the composition of Mm0.3Ml0.7Ni3.55Co0.75Mn0.4Al0.3 was prepared by induction melting. The alloy was mechanical milled for 6h, 15h, 40h and 50h, respectively. The microstructures of alloys were analyzed by the x-ray diffraction. The peaks of the XRD spectrum caused by crystallite and micro-strain were separated by the approximate function and least square method. The results show that the Mm0.3Ml0.7Ni3.55Co0.75Mn0.4Al0.3 alloys milled for 6h consist of nano-crystalline and polycrystalline phase. The lattice parameters and the volume of alloy increase but the crystallite sizes decrease with increasing of milling time. The alloys milled for 40h or 50h transform partly into amorphous structures. The maximum discharge capacities of alloys decrease with increasing of the milling time. The cycle stabilities of the milled alloys are significantly improved with increasing of the milling time. The optimal milling time for the Mm0.3Ml0.7Ni3.55Co0.75Mn0.4Al0.3 alloy is 6h. The maximum discharge capacity of the alloy is 290mAh/g and the capacity conservation rate is 0.81 after 60 times of charge-discharge cycles. Keywords: Hydrogen storage alloy; Mechanical milling; Phase structure; Electrochemical properties; 目 录 TOC \o 1-3 \h \z \u HYPERLINK \l _Toc231668005 第一章 绪 论 PAGEREF _Toc231668005 \h 1 HYPERLINK \l _Toc231668006 1.1引言 PAGEREF _Toc231668006 \h 1 HYPERLINK \l _Toc231668007 1.2氢能简介 PAGEREF _Toc231668007 \h 1 HYPERLINK \l _Toc231668008 1.3