改性蒙脱石对废水中Cr6的吸附性能研究.DOCVIP

doi：10.3969/j.issn.1007-7545.2018.12.014改性蒙脱石对废水中Cr6+ doi：10.3969/j.issn.1007-7545.2018.12.014 李俊翰，孙宁，马兰，杨绍利 （攀枝花学院，四川 攀枝花 617000） 摘要：以蒙脱石为原料、硫酸为改性剂，采用正交试验研究了改性时间、硫酸浓度和固液比对蒙脱石吸附废水中Cr6+吸附效果的影响。研究表明，改性后的蒙脱石层间距增大，吸附活性增强，纯度提高，具有较好的吸附性能。在改性时间180 min、硫酸浓度2 mol/L、固液比1︰4时，蒙脱石对Cr6+的去除率达到77.99%，较原样提高24.26个百分点。当吸附时间120 min、固液比1︰25、pH=5、Cr6+初始浓度10 mg/L时，改性蒙脱石对Cr6+的去除率为87.95%，较原样提高了34.22个百分点。改性蒙脱石对Cr6+的吸附更符合Freundlich等温吸附方程式，拟合系数为0.999 19，吸附方式更符合多分子层吸附，是可逆吸附。 关键词：蒙脱石；改性；废水；Cr6+；吸附性能 中图分类号：X703 文献标志码：A 文章编号：1007-7545（2018）12-0000-00 Adsorption Characteristics of Modified Montmorillonite on Cr6+ in Wastewater LI Jun-han, SUN Ning, MA Lan, YANG Shao-li (Panzhihua University, Panzhihua 617000, Sichuan, China) Abstract：Effects of modification time, sulfuric acid concentration, and L/S on adsorption behavior of Cd6+ in wastewater with montmorillonite were investigated by orthogonal experiments applying sulfuric acid as surface modifier agents. The results indicate that modified montmorillonite has good adsorption performance by enlargement interlayer spacing of modified montmorillonite, high adsorption activity and purity. Cd6+ removal rate is 77.99%, which is 24.26 percent point higher than that of original sample, under the modification conditions including modification time of 180 min, sulfuric acid concentration of 2 mol/L, and L/S=4/1. Cd6+ removal rate by modified montmorillonite is 87.95%, which is 34.22 percent point higher than the original sample, under the modification conditions including adsorption time of 120 min, L/S=25/1, pH value of 5, and initial concentration of Cr6+ of 10 mg/L. Adsorption of modified montmorillonite on Cd6+ is of multi-layer and reversible, which meets Freundlich Isotherm Model (R2=0.999 19). Key words：montmorillonite; modification; wastewater; Cr6+; adsorptive characteristic 蒙脱石是由颗粒极细的含水硅铝酸盐构成的2︰1型层状矿物，是黏土矿物的主要组分。蒙脱石特殊的晶体构造使其具有良好的吸附性、阳离子交换性、催化活性等优点[1-3]，因而蒙脱石常应用在环保、化工、建材、冶金、医药等领域[4-6]。蒙脱石可作为催化剂、催化剂载体、吸附剂使用，并且用于环境污染治理方面上，特别是在水环境的污染处理技术上作为吸附剂使用有较好