以溶胶凝胶法制备氧化锌粉体於降解偶氮染料之研究-国立高雄科技大学.doc

中文摘要 本研究以溶膠-凝膠法製備氧化鋅奈米粉體。起始原料為乙醯丙酮鋅，改變不同劑量之配位劑及分散劑，經由溶液的混合、水解及縮聚合反應製備氧化鋅，主要以探討氧化鋅奈米粉體的製程參數及不同煆燒溫度對奈米粉體的型態微結構之影響，並藉由光分解偶氮染料之光催化實驗，進一步了解粉體微結構的差異對降解有機染料效果之影響。製程中添加醋酸做為配位劑，並以羥丙基纖維素做為分散劑。實驗中以 XRD、 TGA/DTA、 FT-IR、BET、 FE-SEM 及 UV-Vis 對氧化鋅奈米粉體做分析。 實驗發現，添加配位劑後之參數所製備氧化鋅粉體，其表面型態由微粒狀轉為棒狀結構，而一階降解反應速率常數可由 0.00719 min-1 提升至 0.03707 min-1。當製備條件相同(相同添加物及添加量)時，粉體比表面積為影響染料降解反應速率的主要因素；製備條件不同時，降解反應速率則受到表面型態影響大於比表面積，棒狀結構粉體之一階降解反應速率大於微粒狀結構粉體。 英文摘要 In this study, ZnO nanopowders were prepared by a sol-gel method, using [Bis(acetylacetonato)zinc(II)] as starting material. The influences of ligand agent and dispersing agent on the characterization of gel powders were also studied. The powders can be prepared via the procedures of mixing, hydrolysis and condensation reaction. The relationship between photocatalytic activity and microstructure, surface area were investigated. The ZnO nanopowders should be characterized by XRD, TGA/DTA, BET, FE-SEM and UV-Vis. The morphology of ZnO powders prepared with ligand agent can change from particulates to rod-like shape, the reaction rate constant (k) was improved from 0.00719 to 0.03707 min-1. The morphology of ZnO particles is very sensitive to the preparation conditions. Results indicated that the photocatalytic activity of ZnO powder depends on surface area for the same original ZnO powders prepared by equal conditions other than the different in calcination temperature. However, no direct relationship between photocatalytic activity and surface area was found for the differently original ZnO powders prepared by different conditions. Instead, the particle morphology significantly affects its photocatalysis. 目錄 中文摘要 ……………………………………………………… Ⅰ 英文摘要 ……………………………………………………… Ⅱ 致謝 ……………………………………………………… Ⅲ 總目錄 ……………………………………………………… Ⅳ 表目錄 ……………………………………………………… Ⅷ 圖目錄 ……………………………………………………… Ⅸ 第一章 緒論………………………………………………… 1 1-1 前言…………………………………………… 1 1-2 研究動機……………………………………… 2 1-3 研究目的……………………………………… 4 第二章 文獻回顧…………………………………………… 6 2-1 氧化鋅 ( ZnO ) 基本性質…………………… 6 2-1