特丁津聚3-硫噻吩丙二酸分子印迹敏感膜传感器的制备及其性能研究论文-毕业(学术)论文设计.docVIP

PAGE 河南科技学院新科学院 2012届本科生毕业论文 论文题目：特丁津聚3-硫噻吩丙二酸分子印迹敏感膜传感器的制备及其性能研究 学生姓名: 朱 颜 芳 所在院系：化学工程系 所学专业：化学工程与工艺 导师姓名：陈 军 完成时间: 2012年5月 特丁津聚3-硫噻吩丙二酸分子印迹敏感膜传感器 的制备及其性能研究 摘要 本文报道了一种对特丁津有识别特性的分子印迹膜传感器制备，即在模板分子特丁津，支持电解质LiCl，通过循环伏安技术在金电极表面以3-硫噻吩丙二酸为功能单体，制备特丁津的分子印迹聚3-硫噻吩丙二酸敏感膜电化学传感器。利用差分脉冲伏安法对分子印迹膜的影响因素进行了筛选和优化，对分子印迹和非印迹聚合膜行为进行了评价，确定了聚合膜最佳聚合条件和配方，考察了支持电解质、聚合圈数、扫描电位范围、酸度等对特丁津的响应情况；同时检测了此方法对三嗪类结构类似化合物的选择性；建立实际样品的测定方法以及样品的重现性等内容。实验表明，该分子印迹膜对特丁津具有良好的选择性和灵敏度。特丁津的浓度在0.02mmol/L-0.12mmol/L范围内具有良好的线性关系(线性相关系数R=0．99167)，检出限可达0.02mmol/L。将此传感器用于水样中特丁津的测定，回收率在88.5％-92.0％之间，取得了很好的结果。 关键词：特丁津，3-硫噻吩丙二酸，分子印迹，电化学传感器，差分脉冲伏安法 Terbuthylazine 3-Thiophene sulfur malonic acid preparation and performance research of molecular imprinted film sensor Abstract This paper reports a terbuthylazine recognition property of molecular imprinted membrane preparation, that is, with and without the template (terbuthylazine) cases, by cyclic voltammetry technique on gold electrode surface in 3-Thiophene sulfur malonic acid functional monomers, preparation of molecularly imprinted polymer of Ding Jin 3-Thiophene sulfur malonic acid-sensitive membrane electrochemical sensors. This experimental main using difference pulse VA method on molecular imprinted film of effect factors for has filter and optimization, on molecular imprinted and non-imprinted aggregate film behavior for has evaluation, determines has aggregate film best aggregate conditions and formula, investigation has support electrolytic mass, and aggregate ring number, and scan potential range, and acidity, on terbuthylazine of response situation; while detection has this method on three effects class structure similar compounds of selective; established actual samples of determination method and samples of reproduce sexual, content. Experiments show that the molecular imprinted film of terbuthylazine with good selectivity and sensitivity. Terbuthylazine is well within the range of concentrations in 0.02mmol/L~0.12mmol/L of linear relati