离子交换固相萃取-食品安全质量检测学报.PDF

5 10 Vol. 5 No. 10 2014 10 Journal of Food Safety and Quality Oct. , 2014 -- * 高 洁, 陈达炜, 东思源, 苗 虹 , 赵云峰 (, , 100021) 摘 要: 目的 -(UPLC-MS/MS)方法 /(1:1, v:v), , Waters Acquity UPLC BEH HILIC(2.1 mm × 100 mm, 1.7 μm), 结果 0. 5~100.0 μg/L , (r)0. 9996 μg/kg 20 μg/kg2040100 μg/kg 3 , 100.1%~103.9%, 4.7%~8.9% 结论 , 关键词: ; ; -; Rapid determination of urotropine in dried beancurd sticks by ultra-performance liquid chromatography-tandem mass spectrometry coupled with ion exchange solid phase extraction * GAO Jie, CHEN Da-Wei, DONG Si-Yuan, MIAO Hong , ZHAO Yun-Feng (Key Laboratory of Food Safety Risk Assessment, Ministry of Health, China National Center for Food Safety Risk Assessment, Beijing 100021, China) ABSTRACT: Objective To establish a method for the determination of urotropine in dried beancurd sticks by ultra-performance liquid chromatography-tandem mass spectrometry (UPLC-MS/MS). Methods Samples were ultrasonically extracted by acetonitrile/water (1:1, v:v), and then purified by cation exchange solid phase extraction. The analytes were separated on a Waters Acquity UPLC BEH HILIC column (2.1 mm × 100 mm, 1.7 μm) and detected by positive electrospray ionization in multiple r