粉煤灰低温烧成多孔材料及孔结构的调控机制-材料工程专业论文.docxVIP

万方数据 万方数据 Abstract The morphology of the pores and the pores size distribution have a great influence on the mechanical property, the heat-insulating property and the sound absorption performance of the porous materials. In this thesis fly ash was used as the main materials and the foaming gas was from the reaction of Na2CO3 and SiO2, the Na2O-CaO-SiO2-B2O3-F (NCSBF) porous materials were prepared by a low temperature melt foaming process, we have studied how to control the amount of the gas in the porous materials from the gas generation process and the gas dissipation process; we put forward the thoughts that solving the problem by controling the foaming process and study the mechanism of the action of SiC and Si on the pore structure respectively. Research on the amount of gas inside the porous materials has showed that: the apparent activation energy of the reaction of Na2CO3 and SiO2 is 207KJ/mol and the apparent activation factor is 1.96×108min-1, However, When this reaction in the mixtures the apparent activation energy is 86kJ/mol and the apparent activation factor is 6.47×103min-1, it must be the other ingredients which help to reduce the apparent activation energy and the apparent activation factor; Due to the weak process of the gas escaping under 850℃ in the porous materials, we just need to control the generation process of the gas inside the porous materials, when we improved the heating-rate there will be less gas loss in the molt. When increase the heating-rate from 5℃/min to 20℃/min, the volume density of the porous materials will be reduced from 0.72g/cm3 to 0.66g/cm3 Research on the effects of the SiC particles addition on the porous materials has showed that: the particle size of the SiC in the molt of the Na2O-CaO-SiO2-B2O3-F porous materials decreased with oxidation time, when the addition of the SiC is 3%. The oxidation time is 4h, the particle size of the SiC will be ruduced from 196um to 150.7μm, then the particle size